Formylmethyl

Base Information

• Chemical Name: Formylmethyl
• CAS No.: 4400-01-5
• Molecular Formula: C₂H₃O
• Molecular Weight: 43.0452
• DSSTox Substance ID: DTXSID50219180
• Nikkaji Number: J371.062I,J712.352C
• Metabolomics Workbench ID: 56723
• Mol file: 4400-01-5.mol

Synonyms:formylmethyl;Vinyloxy radical;2-oxoethyl;6912-06-7;Vinoxy radical;2-Oxoethyl radical;CHEBI:46886;DTXSID50219180;4400-01-5

Chemical Property of Formylmethyl

Chemical Property:

• XLogP3: -0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 43.018389715
• Heavy Atom Count: 3
• Complexity: 10.3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2]C=O

Technology Process of Formylmethyl

There total 5 articles about Formylmethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethene (74-85-1) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + methyl radical (2229-07-4) + methylene (2465-56-7) + formyl radical (2597-44-6) + vinyloxyl (6912-06-7,4400-01-5)

Guidance literature:

With mercury; dinitrogen monoxide; under 0.003 Torr; Product distribution; Irradiation; var. conc.;

DOI:10.1063/1.451765

Reference yield:

1-butylene (106-98-9,9003-28-5) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + formyl radical (2597-44-6) + vinyloxyl (6912-06-7,4400-01-5)

Guidance literature:

With oxygen; at 25 ℃; under 0.03 Torr; Yield given. Yields of byproduct given; Irradiation; in gaseous SO₂;

DOI:10.1021/j100156a038

Reference yield:

propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + formyl radical (2597-44-6) + vinyloxyl (6912-06-7,4400-01-5)

Guidance literature:

With oxygen; at 25 ℃; under 0.03 Torr; Product distribution; Irradiation; in gaseous SO₂; branching ratios; other terminal olefins;

DOI:10.1021/j100156a038

upstream raw materials:

1-butylene

propene

methylene

acetaldehyde

Downstream raw materials:

cis-nitrous acid

acetaldehyde

Refernces

• 1、 Koda, Seiichiro,Endo, Yasuki,Tsuchiya, Soji,Hirota, Eizi. "Branching Ratios in O(3P) Reactions of Terminal Olefins Studied by Kinetic Microwave Absorption Spectroscopy". . p. 1241 - 1244. Retrieved 2007/10/02.
• 2、 Boehland, T.,Dobe, S.,Temps, F.,Wagner, H. Gg.. "Kinetics of the Reactions between CH2(3B1)-Radicals and Saturated Hydrocarbons in the Temperature Range 296 K . p. 1110 - 1116. Retrieved 2007/10/02.