Silane, (cyclohexyloxy)triethyl-

Base Information

• Chemical Name: Silane, (cyclohexyloxy)triethyl-
• CAS No.: 4419-18-5
• Molecular Formula: C12H26OSi
• Molecular Weight: 214.423
• DSSTox Substance ID: DTXSID40464384
• Nikkaji Number: J568.867A
• Wikidata: Q82289676
• Mol file: 4419-18-5.mol

Synonyms:Silane, (cyclohexyloxy)triethyl-;4419-18-5;(cyclohexyloxy)triethylsilane;DTXSID40464384

Chemical Property of Silane, (cyclohexyloxy)triethyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 214.175291983
• Heavy Atom Count: 14
• Complexity: 140

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC[Si](CC)(CC)OC1CCCCC1

Technology Process of Silane, (cyclohexyloxy)triethyl-

There total 19 articles about Silane, (cyclohexyloxy)triethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triethylsilane (617-86-7) + cyclohexanol (108-93-0) → triethyl-cyclohexyloxy-silane (4419-18-5)

Guidance literature:

{Rh₂(OAc)3[(R)-PhCH₂SCH(Me)C(O)OEt]2}BF₄; In dichloromethane; at 50 ℃; for 24h;

DOI:10.1002/adsc.200700167

Reference yield: 97.0%

triethylsilane (617-86-7) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) → triethyl-cyclohexyloxy-silane (4419-18-5)

Guidance literature:

cyclohexanone; With C₈H₁₀BiCl₂N; C₄H₆AgN₂⁽¹⁺⁾*C₂₄H₁₂BCl₈^(1-); In dichloromethane-d2; at 25 ℃;

triethylsilane; In dichloromethane; at 25 ℃;

DOI:10.1002/chem.202002006

Reference yield: 90.0%

triethylsilyl chloride (994-30-9) + cyclohexanol (108-93-0) → triethyl-cyclohexyloxy-silane (4419-18-5)

Guidance literature:

With triethylamine; at 20 ℃; for 0.0333333h; Inert atmosphere;

DOI:10.1002/jccs.201300586

upstream raw materials:

triethylsilyl chloride

Cyclohexyloxy-tributyl-stannan

triethylsilane

cyclohexanone

Refernces

• 1、 Bai, Yuna,Chan, Yi-Chen,Chen, Hsing-Yin,Chen, Hsuan-Ying,Chen, Wen-Ching,Li, Chen-Yu,Ong, Tiow-Gan,Tseng, Mei-Chun,Wu, Ying-Yann,Yap, Glenn P. A.,Zhao, Lili. "Synergistic Catalysis by Br?nsted Acid/Carbodicarbene Mimicking Frustrated Lewis Pair-Like Reactivity". supporting information. p. 19949 - 19956. Retrieved 2021/08/03.
• 2、 Kannan, Ramkumar,Balasubramaniam, Selvakumar,Kumar, Sandeep,Chambenahalli, Raju,Jemmis, Eluvathingal D.,Venugopal, Ajay. "Electrophilic Organobismuth Dication Catalyzes Carbonyl Hydrosilylation". supporting information. p. 12717 - 12721. Retrieved 2020/09/09.