tert-Butylisopropyl sulfide

Base Information

• Chemical Name: tert-Butylisopropyl sulfide
• CAS No.: 44657-76-3
• Molecular Formula: C7H16S
• Molecular Weight: 132.26700
• Mol file: 44657-76-3.mol

Synonyms:tert-Butyl-isopropyl-sulfid;Propane, 2-methyl-2-[(1-methylethyl)thio]-;isopropyl t-butyl sulphide;2-isopropylsulfanyl-2-methyl-propane;tert-butyl-isopropyl-sulfane;isopropyl tert-butyl sulfide;tert-Butyl Isopropyl sulfide;

Chemical Property of tert-Butylisopropyl sulfide

Chemical Property:

• Vapor Pressure: 9.05mmHg at 25°C
• Boiling Point: 136.6oC at 760 mmHg
• Flash Point: 16.1oC
• PSA: 25.30000
• Density: 0.834g/cm3
• LogP: 2.92650

Purity/Quality:

99% ^*data from raw suppliers

TERT-BUTYL ISOPROPYL SULFIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of tert-Butylisopropyl sulfide

There total 6 articles about tert-Butylisopropyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-methylpropan-2-thiol (75-66-1) + isopropyl bromide (75-26-3) → 2-methyl-2-[(1-methylethyl)thio]-propane (44657-76-3)

Guidance literature:

With potassium hydroxide; In methanol; Heating;

DOI:10.1039/P19810001826

Reference yield:

2-methylpropan-2-thiol (75-66-1) → 2-methyl-2-[(1-methylethyl)thio]-propane (44657-76-3)

Guidance literature:

With sodium hydroxide; tetrabutylammomium bromide; water;

DOI:10.1246/bcsj.56.1249

Reference yield:

2-propanethiol (75-33-2) + isobutene (115-11-7,15220-85-6) → 2-methyl-2-[(1-methylethyl)thio]-propane (44657-76-3)

Guidance literature:

With sulfuric acid;

upstream raw materials:

2-propanethiol

isobutene

tert-butyl alcohol

2-methylpropan-2-thiol

Downstream raw materials:

2-hydroxy-2,2-bis-(p-fluorophenyl)-1,1-dimethylethyl t-butylsulphoxide

2-hydroxy-1,1-dimethyl-2,2-bis-(p-tolyl)ethyl t-butyl sulphoxide

2-hydroxy-1,1-dimethyl-2,2-diphenylethyl t-butyl sulphoxide

Isopropyl-<2,4-dinitro-phenyl>-disulfid

Refernces

• 1、 -. "25-SO2-SUBSITUTED ANALOGS OF 1α,25-DIHYDROXYVITAMIN D3". Page 91-92. . Retrieved 2010/02/07.
• 2、 Yamamoto, Tamotsu,Kakimoto, Masa-aki,Maejima, Takeshi,Okawara, Makoto. "Preparation of Alkanesulfenamides by Selective Elimination of t-Butyl Group in S-Alkyl-S-t-butylsulfilimines". . p. 1249 - 1250. Retrieved 2007/10/02.