Diisopropyl vinylphosphonate

Base Information

• Chemical Name: Diisopropyl vinylphosphonate
• CAS No.: 4472-27-9
• Molecular Formula: C8H17O3P
• Molecular Weight: 192.195
• DSSTox Substance ID: DTXSID80499872
• Nikkaji Number: J877.215K
• Wikidata: Q82351067
• Mol file: 4472-27-9.mol

Synonyms:diisopropyl vinylphosphonate;4472-27-9;SCHEMBL4905870;Dipropan-2-yl ethenylphosphonate;DTXSID80499872;Vinyl-phosphonic acid diisopropyl ester

Chemical Property of Diisopropyl vinylphosphonate

Chemical Property:

• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 192.09153140
• Heavy Atom Count: 12
• Complexity: 173

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(C)OP(=O)(C=C)OC(C)C

Technology Process of Diisopropyl vinylphosphonate

There total 2 articles about Diisopropyl vinylphosphonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triisopropyl phosphite (116-17-6) + 1,2-dichloro-ethane (107-06-2,52399-93-6) → diisopropyl hydrogenphosphonate (1809-20-7) + triisopropyl phosphate (513-02-0) + diisopropyl vinylphosphonate (4472-27-9) + diisopropyl 2-chloroethylphosphonate (25131-74-2) + tetra-iso-propyl ester of ethylidenediphosphonic acid (64630-16-6)

Guidance literature:

for 1152h; Mechanism; Rate constant; Heating;

Reference yield:

triisopropyl phosphite (116-17-6) + 1-Bromo-2-chloroethane (107-04-0) → diisopropyl hydrogenphosphonate (1809-20-7) + triisopropyl phosphate (513-02-0) + diisopropyl vinylphosphonate (4472-27-9) + diisopropyl 2-chloroethylphosphonate (25131-74-2) + tetra-iso-propyl ester of ethylidenediphosphonic acid (64630-16-6)

Guidance literature:

for 24h; Mechanism; Rate constant; Heating;

Reference yield: 98.0%

diisopropyl vinylphosphonate (4472-27-9) + 4-fluoro-1-iodobenzene (352-34-1) → C14H20FO3P

Guidance literature:

With diamminedichloropalladium(II); diisopropylamine; In water; at 80 ℃; for 6h; Green chemistry;

DOI:10.1039/c7ra06464k

upstream raw materials:

triisopropyl phosphite

1,2-dichloro-ethane

1-Bromo-2-chloroethane

Downstream raw materials:

1-[Methyl-(2-phosphanyl-ethyl)-phosphanyl]-2-phosphanyl-ethane

3.6-Diphenyl-3.6-diphosphaoctan-1.8-diylphosphin

[2-(Hydroxy-phenyl-amino)-ethyl]-phosphonic acid diisopropyl ester

(2-Chloro-1-phenylsulfanyl-ethyl)-phosphonic acid diisopropyl ester

Refernces