LITHIUM DIPHENYLPHOSPHIDE

Base Information

• Chemical Name: LITHIUM DIPHENYLPHOSPHIDE
• CAS No.: 4541-02-0
• Molecular Formula: C₁₂H₁₀LiP
• Molecular Weight: 192.126
• Mol file: 4541-02-0.mol

Synonyms:lithium diphenylphosphanide;lithium diphenylphosphide;lithium diphenylphosphinite;

Chemical Property of LITHIUM DIPHENYLPHOSPHIDE

Chemical Property:

• PSA: 13.59000
• LogP: 2.31590

Purity/Quality:

97% ^*data from raw suppliers

LithiumDiphenylphosphide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of LITHIUM DIPHENYLPHOSPHIDE

There total 23 articles about LITHIUM DIPHENYLPHOSPHIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

diphenylphosphane (829-85-6) → lithium diphenylphosphide (65567-06-8,4541-02-0)

Guidance literature:

diphenylphosphane; With n-butyllithium; In hexane; at -20 ℃; Inert atmosphere; Schlenk technique;

In hexane; at 20 ℃; for 5h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c7cy01561e

Reference yield: 99.78%

chloro-diphenylphosphine (1079-66-9,74391-44-9) → lithium diphenylphosphide (65567-06-8,4541-02-0)

Guidance literature:

With lithium; In tetrahydrofuran; mineral oil; at 56 ℃; Product distribution / selectivity; Inert atmosphere;

Reference yield:

triphenylphosphine (603-35-0) → phenyllithium (591-51-5) + lithium diphenylphosphide (65567-06-8,4541-02-0)

Guidance literature:

With lithium; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere;

DOI:10.1039/b900591a

upstream raw materials:

chloro-diphenylphosphine

triphenylphosphine

diphenylphosphane

1,2-bis-(diphenylphosphino)ethane

Downstream raw materials:

(2-methoxyethyl)diphenylphosphine

(2-ethoxyethyl)(diphenyl)phosphine

C₁₈H₁₀F₈P₂

C₄₂H₃₀F₆P₄

Refernces

• 1、 Mohammadnezhad, Gholamhossein,Abad, Saeed,Farrokhpour, Hossein,G?rls, Helmar,Plass, Winfried. "Electrocatalytic property, anticancer activity, and density functional theory calculation of [NiCl(P^N^P)]Cl.EtOH". . . Retrieved 2021.
• 2、 Gallop, Chris W.D.,Bobin, Mariusz,Hourani, Petra,Dwyer, Jessica,Roe, S. Mark,Viseux, Eddy M. E.. "Investigation of the reductive cleavage of BINAP and application to the rapid synthesis of phospholes". . p. 6522 - 6528. Retrieved 2013.
• 3、 Rong, Mark K.,Holtrop, Flip,Bobylev, Eduard O.,Nieger, Martin,Ehlers, Andreas W.,Slootweg, J. Chris,Lammertsma, Koop. "Atypical and Asymmetric 1,3-P,N Ligands: Synthesis, Coordination and Catalytic Performance of Cycloiminophosphanes". supporting information. p. 14007 - 14016. Retrieved 2021/09/09.