Phenyl(triphenylgermyl)methanone

Base Information

• Chemical Name: Phenyl(triphenylgermyl)methanone
• CAS No.: 4639-86-5
• Molecular Formula: C25H20GeO
• Molecular Weight: 409.023
• DSSTox Substance ID: DTXSID80543329
• Nikkaji Number: J2.449.065C
• Wikidata: Q82420169
• Mol file: 4639-86-5.mol

Synonyms:Phenyl(triphenylgermyl)methanone;4639-86-5;DTXSID80543329

Chemical Property of Phenyl(triphenylgermyl)methanone

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 410.0725930
• Heavy Atom Count: 27
• Complexity: 417

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)[Ge](C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Phenyl(triphenylgermyl)methanone

There total 1 articles about Phenyl(triphenylgermyl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

benzoic acid methyl ester (93-58-3,5705-52-2,80226-58-0) + triphenylgermyl lithium (3839-32-5) → benzoyl-triphenylgermane (4639-86-5)

Guidance literature:

In tetrahydrofuran; byproducts: LiOCH3, Ge(C6H5)3H; dropwise addn. of organic compd. (via syringe) to a soln. of Li-compd. (prepd. from GePh3 and BuLi in hexane) at room temp. under Ar, stirred for 10 min; quenched with aq. NH4Cl, organic layer extd. (ether), dried over MgSO4, evapd., flash chromy.;

DOI:10.1246/cl.1985.1829

Reference yield:

Cyclohexyl iodide (626-62-0) + benzoyl-triphenylgermane (4639-86-5) → cyclohexylcyclohexane (92-51-3) + cyclohexane (110-82-7,25012-93-5) + Cyclohexyl phenyl ketone (712-50-5) + cyclohexene (110-83-8)

Guidance literature:

In benzene-d6; for 2h; Title compound not separated from byproducts; Ambient temperature; Irradiation;

DOI:10.1016/S0022-328X(96)06677-6

Reference yield:

1-iodo-butane (542-69-8) + benzoyl-triphenylgermane (4639-86-5) → octane (111-65-9) + phenyl butyl ketone (1009-14-9)

Guidance literature:

In benzene-d6; for 1h; Title compound not separated from byproducts; Ambient temperature; Irradiation;

DOI:10.1016/S0022-328X(96)06677-6

upstream raw materials:

benzoic acid methyl ester

triphenylgermyl lithium

Downstream raw materials:

octane

phenyl butyl ketone

cyclohexylcyclohexane

cyclohexane

Refernces