Cyclodecanone

Base Information

• Chemical Name: Cyclodecanone
• CAS No.: 1502-06-3
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Hs Code.: 29142990
• European Community (EC) Number: 216-119-8
• NSC Number: 90293
• UNII: 3N73MQZ9ZJ
• DSSTox Substance ID: DTXSID60164490
• Nikkaji Number: J4.538A
• Wikidata: Q20054512
• Mol file: 1502-06-3.mol

Synonyms:CYCLODECANONE;1502-06-3;cyclodecan-1-one;UNII-3N73MQZ9ZJ;3N73MQZ9ZJ;EINECS 216-119-8;NSC 90293;NSC-90293;cyclodecanon;NSC90293;Cyclodecanone, 97%;SCHEMBL1667004;SXOZDDAFVJANJP-UHFFFAOYSA-;DTXSID60164490;MFCD00003713;AKOS009156487;AS-56504;FT-0624162;EN300-61158;A1-50295;J-008670;Q20054512

Chemical Property of Cyclodecanone

Chemical Property:

• Vapor Pressure: 0.06mmHg at 25°C
• Melting Point: 21-24 °C(lit.)
• Refractive Index: n20/D 1.482(lit.)
• Boiling Point: 232.1 °C at 760 mmHg
• Flash Point: 82.2 °C
• PSA: 17.07000
• Density: 0.886 g/cm³
• LogP: 3.08000
• Storage Temp.: 2-8°C
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 154.135765193
• Heavy Atom Count: 11
• Complexity: 106

Purity/Quality:

98%,99%, ^*data from raw suppliers

Cyclodecan-1-one 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCCCC(=O)CCCC1

Technology Process of Cyclodecanone

There total 71 articles about Cyclodecanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

cyclodecanol (1502-05-2) → cyclodecanone (1502-06-3)

Guidance literature:

With nickel; In benzene; for 7h; Heating;

DOI:10.1021/jo00376a099

Reference yield: 95.0%

2-iodo-cyclodecanone → cyclodecanone (1502-06-3)

Guidance literature:

With triethyl borane; ytterbium(III) triflate; allyl-trimethyl-silane; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/b901943j

Reference yield: 82.0%

→ 1,10-decanedioic acid (111-20-6,26776-29-4) + cyclodecanone (1502-06-3)

Guidance literature:

upstream raw materials:

cycloactanone

ethyl N-methyl-N-nitrosocarbamate

cyclononanone

1,11-undecanedinitrile

Downstream raw materials:

2,7-Heptamethylen-4,5-benzotropon

3,4,5,6,7,8-hexahydro-2H-naphthalen-1-one

trans-1-decalone

cycloundecanone

Refernces

• 1、 Bhagwat et al.. "". . p. C27. Retrieved 1974.
• 2、 Hajimohammadi, Mahdi,Safari, Nasser,Mofakham, Hamid,Deyhimi, Farzad. "Highly selective, economical and efficient oxidation of alcohols to aldehydes and ketones by air and sunlight or visible light in the presence of porphyrins sensitizers". . p. 991 - 997. Retrieved 2011.
• 3、 Knight, Candice,Perkins, M. John. "Concerning the Mechanism of 'Gif' Oxidations of Cycloalkanes". . p. 925 - 927. Retrieved 1991.
• 4、 Aschmann, Sara M.,Arey, Janet,Atkinson, Roger. "Reactions of OH radicals with C6 - C10 cycloalkanes in the presence of NO: Isomerization of C7 - C10 cycloalkoxy radicals". . p. 14452 - 14461. Retrieved 2011.
• 5、 Lebedeva, Anastasia,Albuquerque, Brunno L.,Domingos, Josiel B.,Lamonier, Jean-Fran?ois,Giraudon, Jean-Marc,Lecante, Pierre,Denicourt-Nowicki, Audrey,Roucoux, Alain. "Ruthenium Trichloride Catalyst in Water: Ru Colloids versus Ru Dimer Characterization Investigations". . p. 4141 - 4151. Retrieved 2019/03/26.
• 6、 Huang, Daria L.,Vinyard, David J.,Blakemore, James D.,Hashmi, Sara M.,Crabtree, Robert H.. "Cp? versus Bis-carbonyl iridium precursors as CH oxidation precatalysts". . p. 199 - 206. Retrieved 2017/11/27.