N-benzyl-N-phenylaniline

Base Information

• Chemical Name: N-benzyl-N-phenylaniline
• CAS No.: 606-87-1
• Molecular Formula: C19H17N
• Molecular Weight: 259.351
• Hs Code.: 2921440000
• European Community (EC) Number: 210-127-5
• DSSTox Substance ID: DTXSID20209412
• Nikkaji Number: J7.005J
• Wikidata: Q83083684
• Mol file: 606-87-1.mol

Synonyms:N-benzyl-N-phenylaniline;606-87-1;N,N-Diphenylbenzylamine;Benzyldiphenylamine;benzyl-diphenyl-amine;Benzenemethanamine, N,N-diphenyl-;C19H17N;EINECS 210-127-5;diphenylbenzylamine;N,N-Diphenylbenzylamin;N-benzyl-N-phenyl-aniline;Benzylamine, N,N-diphenyl-;N,N-Diphenylbenzenemethanamine;SCHEMBL918512;N,N-diphenyl-benzenemethanamine;DTXSID20209412;ADAL1037868;MFCD00092745;STL200437;AKOS005155811;BS-42308;FT-0702536;D97467;A832842;W-105236

Chemical Property of N-benzyl-N-phenylaniline

Chemical Property:

• Vapor Pressure: 6.61E-07mmHg at 25°C
• Melting Point: 88-89℃ (ethanol )
• Refractive Index: 1.642
• Boiling Point: 409.2 °C at 760 mmHg
• Flash Point: 179.4 °C
• PSA: 3.24000
• Density: 1.104 g/cm³
• LogP: 5.02490
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 5.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 259.136099547
• Heavy Atom Count: 20
• Complexity: 239

Purity/Quality:

98%min ^*data from raw suppliers

N,N-DIPHENYLBENZYLAMINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CN(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of N-benzyl-N-phenylaniline

There total 55 articles about N-benzyl-N-phenylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

benzaldehyde (100-52-7) + diphenylamine (122-39-4) → N,N-diphenylbenzylamine (606-87-1)

Guidance literature:

With triethylsilane; bismuth(III) chloride; In acetonitrile; at 20 ℃; for 13h; Reagent/catalyst; Solvent; chemoselective reaction; Inert atmosphere; Green chemistry;

DOI:10.1016/j.tetlet.2014.01.132

Reference yield: 98.0%

benzyl bromide (100-39-0) + diphenylamine (122-39-4) → N,N-diphenylbenzylamine (606-87-1)

Guidance literature:

With potassium hydroxide; PEG methyl ether; In toluene; for 1h; Irradiation;

DOI:10.1016/S0040-4039(00)94235-7

Reference yield: 97.0%

2-(trimethylsilyl)phenyl trifluoromethanesulfonate (88284-48-4) + benzylamine (100-46-9) → N,N-diphenylbenzylamine (606-87-1)

Guidance literature:

With cesium fluoride; In acetonitrile; at 20 ℃; for 72h;

DOI:10.1021/jo0602221

upstream raw materials:

N,N-Diphenylthiobenzamid

sodium diphenylamine

benzyl chloride

diphenylamine

Downstream raw materials:

meso-tetra-N-phenyl-bibenzyl-α,α'-diyldiamine

racem.-tetra-N-phenyl-bibenzyl-α,α'-diyldiamine

((E)-1,2-Diphenyl-vinyl)-diphenyl-amine

benzyl-(4-nitro-phenyl)-phenyl-amine

Refernces

• 1、 -. "Method for catalyzing hydrodesulfurization of thioamide derivative". Paragraph 0064-0068. . Retrieved 2021/07/09.
• 2、 Fan, Qing-Hua,Liu, Xintong,Luo, Zhenli,Pan, Yixiao,Xu, Lijin,Yang, Ji,Yao, Zhen,Zhang, Xin. "BF3·Et2O as a metal-free catalyst for direct reductive amination of aldehydes with amines using formic acid as a reductant". supporting information. p. 5205 - 5211. Retrieved 2021/07/29.