Trichloro(cyclohexylmethyl)silane

Base Information

• Chemical Name: Trichloro(cyclohexylmethyl)silane
• CAS No.: 18388-16-4
• Molecular Formula: C7H13Cl3Si
• Molecular Weight: 231.625
• European Community (EC) Number: 242-265-7
• UNII: 8BAT3GSB9H
• DSSTox Substance ID: DTXSID1066364
• Nikkaji Number: J266.149G
• Wikidata: Q81992963
• Mol file: 18388-16-4.mol

Synonyms:Trichloro(cyclohexylmethyl)silane;(Cyclohexylmethyl)trichlorosilane;18388-16-4;Silane, trichloro(cyclohexylmethyl)-;Cyclohexane, ((trichlorosilyl)methyl)-;EINECS 242-265-7;8BAT3GSB9H;Cyclohexane,[(trichlorosilyl)methyl]-;C7H13Cl3Si;UNII-8BAT3GSB9H;C7-H13-Cl3-Si;trichlorosilylmethylcyclohexane;SCHEMBL1204274;DTXSID1066364;Trichlorosilyl(cyclohexyl)methane;trichloro( cyclohexylmethyl)silane;Trichloro(cyclohexylmethyl)silane #;MFCD00019387;AKOS024334157;(Cyclohexylmethyl)Trichlorosilane;97%;FT-0637686

Chemical Property of Trichloro(cyclohexylmethyl)silane

Chemical Property:

• Vapor Pressure: 0.000777mmHg at 25°C
• Refractive Index: 1.508
• Boiling Point: 220.3 °C at 760 mmHg
• Flash Point: 99.7 °C
• PSA: 0.00000
• Density: 1.173 g/cm³
• LogP: 4.22200
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 229.985210
• Heavy Atom Count: 11
• Complexity: 115

Purity/Quality:

98%,99%, ^*data from raw suppliers

(CYCLOHEXYLMETHYL)TRICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1CCC(CC1)C[Si](Cl)(Cl)Cl

Technology Process of Trichloro(cyclohexylmethyl)silane

There total 5 articles about Trichloro(cyclohexylmethyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

1-methylcyclohex-1-ene (591-49-1) → trichloro(cyclohexylmethyl)silane (18388-16-4)

Guidance literature:

With trichlorosilane; dihydrogen hexachloroplatinate; In isopropyl alcohol; at 120 - 180 ℃;

DOI:10.1007/s11176-005-0114-4

Reference yield:

3-methyl-1-cyclohexene (591-48-0) → trichloro(cyclohexylmethyl)silane (18388-16-4)

Guidance literature:

With dihydrogen hexachloroplatinate(IV) hexahydrate; trichlorosilane; In isopropyl alcohol; at 0 - 100 ℃; for 20h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.9b02695

Reference yield:

4-methylcyclohexene (591-47-9) → trichloro(cyclohexylmethyl)silane (18388-16-4)

Guidance literature:

With dihydrogen hexachloroplatinate(IV) hexahydrate; trichlorosilane; In isopropyl alcohol; at 0 - 100 ℃; for 20h; Inert atmosphere; Schlenk technique; Sealed tube;

DOI:10.1021/acs.orglett.9b02695

upstream raw materials:

1-methylcyclohex-1-ene

(cyclohexylmethyl)magnesium chloride

3-methyl-1-cyclohexene

4-methylcyclohexene

Downstream raw materials:

Cyclohexyl(cyclohexylmethyl)silan

Bicyclohexyl(cyclohexylmethyl)silan

methylenecyclohexane

cyclohexylmethyldihydrogensilane

Refernces

• 1、 Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov. "Hydrosilylation of cyclohexene, 1-methylcyclohexene, and isopropylidenecyclohexane". . p. 1895 - 1899. Retrieved 2007/10/03.