Diazene, phenyl[phenyl(phenylhydrazono)methyl]-, (Z,E)-

Base Information

• Chemical Name: Diazene, phenyl[phenyl(phenylhydrazono)methyl]-, (Z,E)-
• CAS No.: 49624-20-6
• Molecular Formula: C19H16N4
• Molecular Weight: 300.363
• Mol file: 49624-20-6.mol

Synonyms:syn-trans-N,N',C-triphenylformazan;triphenylformazan;(1E,3Z)-1,3,5-triphenyl-formazan;1t.3.5-Triphenyl-cis-formazan;triphenylformazon;1,3,5-triphenyl-formazan;

Chemical Property of Diazene, phenyl[phenyl(phenylhydrazono)methyl]-, (Z,E)-

Chemical Property:

• PSA: 49.11000
• LogP: 5.31720

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diazene, phenyl[phenyl(phenylhydrazono)methyl]-, (Z,E)-

There total 19 articles about Diazene, phenyl[phenyl(phenylhydrazono)methyl]-, (Z,E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

aniline (62-53-3) + benzaldehyde phenylhydrazone (588-64-7) → 1,3,5-triphenylformazan (49624-20-6)

Guidance literature:

aniline; With hydrogenchloride; sodium nitrite; In water; at 0 - 5 ℃;

benzaldehyde phenylhydrazone; With sodium acetate; sodium hydroxide; In methanol; water; at 0 - 5 ℃; for 1h; pH=10 - 12;

DOI:10.1016/j.saa.2009.09.034

Reference yield: 71.0%

aniline (62-53-3) + (E)-1-benzylidene-2-phenylhydrazine (588-64-7) → 1,3,5-triphenylformazan (49624-20-6)

Guidance literature:

With hydrogenchloride; tetrabutylammomium bromide; sodium carbonate; sodium nitrite; 2.) aq. CH₂Cl₂, 5 deg C to 15 deg C, 1 h;

DOI:10.1055/s-1995-3958

Reference yield: 70.0%

benzenediazonium (2684-02-8) + benzaldehyde (100-52-7) + phenylhydrazine (100-63-0) → 1,3,5-triphenylformazan (49624-20-6)

Guidance literature:

benzaldehyde; phenylhydrazine;

benzenediazonium;

DOI:10.1016/j.tetlet.2009.05.086

upstream raw materials:

benzene diazonium chloride

benzaldehyde phenylhydrazone

phenyldiazonium acetate

testosterone

Downstream raw materials:

3-phenylbenzo-1,2,4-triazine

6-(2'-naphthyl)-1,3,5-triphenyl-verdazyl

3-dimethylamino-2,4,6-triphenyl-3,4-dihydro-2H-1,2,4,5-tetrazin-1-yl

1,3,5-triphenylverdazylium picrate

Refernces

• 1、 Tezcan, Habibe,Tokay, Nesrin. "Synthesis, spectroscopy, and quantum-chemical calculations on 1-substituted phenyl-3,5-diphenylformazans". experimental part. p. 54 - 60. Retrieved 2010/03/04.
• 2、 Gilroy, Joe B.,McKinnon, Stephen D. J.,Koivisto, Bryan D.,Hicks, Robin G.. "Electrochemical studies of verdazyl radicals". . p. 4837 - 4840. Retrieved 2008/03/18.