heptan-4-yl hydroperoxide

Base Information

• Chemical Name: heptan-4-yl hydroperoxide
• CAS No.: 761-40-0
• Molecular Formula: C7H16O2
• Molecular Weight: 132.203
• Mol file: 761-40-0.mol

Synonyms:

Chemical Property of heptan-4-yl hydroperoxide

Chemical Property:

• Vapor Pressure: 0.103mmHg at 25°C
• Boiling Point: 196.3°C at 760 mmHg
• Flash Point: 72.5°C
• Density: 0.891g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of heptan-4-yl hydroperoxide

There total 9 articles about heptan-4-yl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 16.0%

4-heptanone (123-19-3) → 4-heptyl hydroperoxide (761-40-0)

Guidance literature:

4-heptanone; With toluene-4-sulfonic acid hydrazide; In ethanol; at 20 ℃; for 4h; Inert atmosphere;

With dimethylsulfide borane complex; In tetrahydrofuran; at 0 ℃;

DOI:10.1021/acs.inorgchem.6b02322

Reference yield:

n-heptane (142-82-5) → n-pentyl methyl ketone (110-43-0) + 1-methylhexyl-hydroperoxide (762-46-9) + 1-heptyl hydroperoxide (764-81-8,51728-68-8) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0) + heptan-3-one (106-35-4)

Guidance literature:

With 2-pyrazylcarboxylic acid; dihydrogen peroxide; oxygen; [n-Bu₄N]VO₃; In acetonitrile; at 23 ℃; for 24h; Product distribution; Mechanism; other alkanes; var. time, with or without H₂O and irradiation;

DOI:10.1016/0040-4020(96)00769-7

Reference yield:

n-heptane (142-82-5) → 1-methylhexyl-hydroperoxide (762-46-9) + 1-heptyl hydroperoxide (764-81-8,51728-68-8) + 3-heptyl hydroperoxide (761-70-6) + 4-heptyl hydroperoxide (761-40-0)

Guidance literature:

With air; dihydrogen peroxide; 2-pyrazylcarboxylic acid; [n-Bu₄N]VO₃; In water; acetonitrile; at 23 ℃; for 3h; Further byproducts given;

DOI:10.1007/BF02495206

upstream raw materials:

n-heptane

4-heptylmethane sulphonate

dihydrogen peroxide

4-heptanone

Downstream raw materials:

heptan-4-ol

heptane-1,4-diol

nonyl alcohol

4-heptanone

Refernces

• 1、 Schmidt, Anna-Corina,Hermsen, Marko,Rominger, Frank,Dehn, Richard,Teles, Joaquim Henrique,Sch?fer, Ansgar,Trapp, Oliver,Schaub, Thomas. "Synthesis of Mono- and Dinuclear Vanadium Complexes and Their Reactivity toward Dehydroperoxidation of Alkyl Hydroperoxides". supporting information. p. 1319 - 1332. Retrieved 2017/02/15.
• 2、 Nizova, Galina V.,Krebs, Bernt,Süss-Fink, Georg,Schindler, Siegfried,Westerheide, Lars,Gonzalez Cuervo, Laura,Shul'pin, Georgiy B.. "Hydroperoxidation of methane and other alkanes with H2O2 catalyzed by a dinuclear iron complex and an amino acid". . p. 9231 - 9237. Retrieved 2007/10/03.