3,3'-DINITRO-BIPHENYL

Base Information

• Chemical Name: 3,3'-DINITRO-BIPHENYL
• CAS No.: 958-96-3
• Molecular Formula: C12H8 N2 O4
• Molecular Weight: 244.207
• Hs Code.: 2904209090
• Mol file: 958-96-3.mol

Synonyms:Biphenyl,3,3'-dinitro- (7CI,8CI); 3,3'-Dinitro-1,1'-biphenyl; 3,3'-Dinitrobiphenyl;m,m'-Dinitrobiphenyl

Chemical Property of 3,3'-DINITRO-BIPHENYL

Chemical Property:

• Boiling Point: 416°Cat760mmHg
• Flash Point: 207.4°C
• PSA: 91.64000
• Density: 1.368g/cm³
• LogP: 4.21640

Purity/Quality:

99%min ^*data from raw suppliers

3,3'-DINITRO-BIPHENYL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3,3'-DINITRO-BIPHENYL

There total 44 articles about 3,3'-DINITRO-BIPHENYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3,3'-dinitrodiphenyliodonium bromide (24163-36-8) → iodobenzene (591-50-4) + 3,3'-dinitro-1,1'-biphenyl (958-96-3)

Guidance literature:

With zinc; palladium(II) acetylacetonate; In tetrahydrofuran; for 0.5h; Ambient temperature;

DOI:10.1246/cl.1983.1165

Reference yield: 89.0%

2-(prop-1-ynyl)-benzyl 2-iodophenyl ether (886862-07-3) + m-nitrobenzene boronic acid (13331-27-6) → 3'-nitro-2-(2-prop-1-ynyl-benzyloxy)-biphenyl + (Z)-3-[1-(6H-dibenzo[b,e]oxepin-11-ylidene)-ethyl]-nitrobenzene (886862-12-0) + 3,3'-dinitro-1,1'-biphenyl (958-96-3)

Guidance literature:

With sodium carbonate; palladium diacetate; In 1,4-dioxane; water; at 70 ℃; for 12h;

DOI:10.1021/ol060289a

Reference yield: 82.0%

3-nitrophenyldiazonium tetrafluoroborate (586-36-7) → 3,3'-dinitro-1,1'-biphenyl (958-96-3) + nitrobenzene (98-95-3,26969-40-4)

Guidance literature:

With copper(I) triflate; In acetonitrile; at 0 - 20 ℃; for 20h;

DOI:10.1016/j.tet.2007.04.016

upstream raw materials:

m-iodonitrobenzene

3-iodochlorobenzene

3-nitroperbenzoic acid

benzoic acid

Downstream raw materials:

N³,N³,N^3',N^3'-Tetrakis-(4-methoxy-phenyl)-biphenyl-3,3'-diamine

3,4,3'-Trinitro-biphenyl

3-amino-3'-nitrobiphenyl

1‐(3‐methoxyphenyl)‐3‐nitrobenzene

Refernces

• 1、 Salim Lew, Tedrick Thomas,Wen Lim, Diane Shu,Zhang, Yugen. "Copper(i)-catalyzed amidation reaction of organoboronic esters and isocyanates". supporting information. p. 5140 - 5143. Retrieved 2015/12/05.
• 2、 Zhou, Lihong,Lu, Wenjun. "Palladium(II)-catalyzed coupling of electron-deficient arenes via C-H activation". scheme or table. p. 2124 - 2127. Retrieved 2012/06/01.