Hydroperoxide, 1-(methylazo)cyclohexyl

Base Information

• Chemical Name: Hydroperoxide, 1-(methylazo)cyclohexyl
• CAS No.: 50265-80-0
• Molecular Formula: C7H14N2O2
• Molecular Weight: 158.2
• Mol file: 50265-80-0.mol

Synonyms:

Chemical Property of Hydroperoxide, 1-(methylazo)cyclohexyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Hydroperoxide, 1-(methylazo)cyclohexyl

There total 2 articles about Hydroperoxide, 1-(methylazo)cyclohexyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexanone methylhydrazone (1567-83-5) → 1-(methylazo)cyclohexyl hydroperoxide (50265-80-0)

Guidance literature:

With oxygen; 5,15,10,20-tetraphenylporphyrin; In dichloromethane-d2; at 0 ℃; for 0.5h; Irradiation;

DOI:10.1021/jo00217a034

Reference yield:

cyclohexanone methylhydrazone (1567-83-5) → α-Methylazo-cyclohexylhydroperoxid (50265-80-0)

Guidance literature:

With oxygen; In pentane;

Reference yield:

ethylbenzene (100-41-4,27536-89-6) + 1-(methylazo)cyclohexyl hydroperoxide (50265-80-0) → methane (34557-54-5,27936-85-2) + ethane (74-84-0) + 2,3-diphenylbutane (1857-74-5,2726-21-8,4539-34-8,4613-11-0,71606-46-7,5789-35-5) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4)

Guidance literature:

at 80 ℃; Product distribution; Mechanism; Rate constant; other temp., energy data: activation energy, δH(excit.), ΔS(excit.);

upstream raw materials:

cyclohexanone methylhydrazone

Downstream raw materials:

methane

ethane

2,3-diphenylbutane

cyclohexanone

Refernces