Ethenylium, 1-methyl-

Base Information

• Chemical Name: Ethenylium, 1-methyl-
• CAS No.: 50457-57-3
• Molecular Formula: C3H5
• Molecular Weight: 41.0727
• Mol file: 50457-57-3.mol

Synonyms:

Chemical Property of Ethenylium, 1-methyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethenylium, 1-methyl-

There total 12 articles about Ethenylium, 1-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

iron monocarbonyl cation (35038-14-3) + 3-chloroprop-1-ene (107-05-1) → FeCl(1+) + C6H10(1+) + FeC3H5Cl(1+) (119909-88-5) + prop-1->3-enylium (1724-46-5,1981-80-2,6067-68-1,15552-77-9,50457-57-3,50457-58-4,65887-19-6,65887-20-9) + iron (1+) (14067-02-8)

Guidance literature:

In gas; reaction with allyl chloride (ca. 1 mTorr) in MS/MS/MS multiquadropole spectrometer (collision gas Ar, 0.7 mTorr; 15-25 eV); according to Beaugrand, C. et al., Int. J. Mass Spectrom. Ion Proc., in press; further products; Kinetics;

DOI:10.1021/ja00191a080

Reference yield:

sulphonium (14701-12-3,18155-21-0) + 1,2-propanediene (463-49-0) → hydrogen sulfide (7783-06-4) + 2-propenyl cation (50457-57-3)

Guidance literature:

In gas; equil. react.; gas phase protonation;

DOI:10.1021/ja00437a047

Reference yield:

sulphonium (14701-12-3,18155-21-0) + prop-1-yne (74-99-7) → hydrogen sulfide (7783-06-4) + 2-propenyl cation (50457-57-3)

Guidance literature:

In gas; equil. react.; gas phase protonation;

DOI:10.1021/ja00437a047

upstream raw materials:

(Z)-2-Butene

trans-2-propenyl bromide

isobutene

propene

Downstream raw materials:

N-Allyl-pyridinium

propene

vinyl cation

C₉H₁₁⁽¹⁺⁾

Refernces

• 1、 Benzi, Paola,Operti, Lorenza,Rabezzana, Roberto. "Ion chemistry in XH4/allene (X = Ge, Si) gaseous mixtures - Formation of X-C bonds". . p. 505 - 512. Retrieved 2007/10/03.
• 2、 Forte, Leonard,Lien, Min H.,Hopkinson, Alan C.,Bohme, Diethard K.. "Gas-phase measurements of the kinetics of BF2(+)-induced polymerization of olefinic monomers". . p. 1576 - 1583. Retrieved 2007/10/02.