(3-Methylcyclopentyl)benzene

Base Information

• Chemical Name: (3-Methylcyclopentyl)benzene
• CAS No.: 5078-75-1
• Molecular Formula: C12H16
• Molecular Weight: 160.259
• Hs Code.: 2902909090
• Mol file: 5078-75-1.mol

Synonyms:1-Phenyl-3-methylcyclopentylbenzen;1-phenyl-3-methylcyclopentane;1-methyl-3-phenyl-cyclopentane;3-methyl-1-phenylcyclopentane;1-Methyl-3-phenylcyclopentan;

Chemical Property of (3-Methylcyclopentyl)benzene

Chemical Property:

• Boiling Point: 230-235 °C
• PSA: 0.00000
• Density: 0.950 g/cm3(Temp: 17 °C)
• LogP: 3.59020

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3-Methylcyclopentyl)benzene

There total 18 articles about (3-Methylcyclopentyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

3-phenyl-1,5-hexadiene (1076-66-0) → 1-Phenyl-3-methylcyclopentylbenzen (5078-75-1) + trans 1-methyl-2-phenylcyclopentane (1560-02-7,4809-94-3,20079-03-2,143005-89-4,143005-90-7)

Guidance literature:

With hydrogen; In benzene; for 0.75h; Ambient temperature;

DOI:10.1021/ja00034a061

Reference yield: 83.0%

[1-(iodomethyl)-4-pentenyl]benzene (410098-30-5) → 1-Phenyl-3-methylcyclopentylbenzen (5078-75-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); 2,2-di-Me-5-[3-(diphenylstannyl)propyl]-1,3-dioxolan-4-one; In benzene; for 3h; Heating;

DOI:10.1021/jo010885c

Reference yield: 74.0%

[(2-phenylhex-5-enyl)seleno]benzene (410098-31-6) → 1-Phenyl-3-methylcyclopentylbenzen (5078-75-1)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); 2,2-di-Me-5-[3-(diphenylstannyl)propyl]-1,3-dioxolan-4-one; In benzene; for 5h; Heating;

DOI:10.1021/jo010885c

upstream raw materials:

3-methylcyclopentanol

benzene

styrene

crotylmagnesium chloride

Downstream raw materials:

acetic acid

benzoic acid

Refernces

• 1、 Baldwin, John E.,Bonacorsi Jr., Samuel. "Stereochemistry of the thermal isomerizations of (1/R,2R)-1-((E)-Styryl)-2-methylcyclopropane to 3-phenyl-4-methylcyclopentenes". . p. 10621 - 10627. Retrieved 2007/10/02.
• 2、 Miethchen, Ralf,Steege, Sigrid,Kroeger, Carl-Friedrich. "Acid-catalyzed Reactions of Aromatic Hydrocarbons with Alkanes and Cycloalkanes. X. Alkylations with Cyclohexane". . p. 823 - 834. Retrieved 2007/10/02.