Hydroperoxide, cyclooctyl

Base Information

• Chemical Name: Hydroperoxide, cyclooctyl
• CAS No.: 5130-47-2
• Molecular Formula: C8H16O2
• Molecular Weight: 144.214
• DSSTox Substance ID: DTXSID30449100
• Nikkaji Number: J651.583E
• Mol file: 5130-47-2.mol

Synonyms:cyclooctyl hydroperoxide;Hydroperoxide, cyclooctyl;5130-47-2;SCHEMBL3416195;DTXSID30449100

Chemical Property of Hydroperoxide, cyclooctyl

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 144.115029749
• Heavy Atom Count: 10
• Complexity: 75.3

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCCC(CCC1)OO

Technology Process of Hydroperoxide, cyclooctyl

There total 4 articles about Hydroperoxide, cyclooctyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

Cyclooctan (292-64-8) → cycloactanone (502-49-8) + cyclooctylhydroperoxide (5130-47-2)

Guidance literature:

With HO₄₀PVW₁₁^(14-)*4C₁₆H₃₆N⁽¹⁺⁾; dihydrogen peroxide; In acetonitrile; at 80 ℃; for 12h; Inert atmosphere;

DOI:10.2298/JSC111124040T

Reference yield: 69.0%

Cyclooctan (292-64-8) → cycloactanone (502-49-8) + cyclooctanol (696-71-9) + cyclooctylhydroperoxide (5130-47-2)

Guidance literature:

With O₄₀PV₂W₁₀^(8-)*5C₁₆H₃₆N⁽¹⁺⁾; dihydrogen peroxide; In acetonitrile; at 80 ℃; for 9h; Inert atmosphere;

DOI:10.2298/JSC111124040T

Reference yield:

Cyclooctan (292-64-8) → Cyclooctene oxide (286-62-4) + cycloactanone (502-49-8) + cyclooctanol (696-71-9) + cyclooctylhydroperoxide (5130-47-2)

Guidance literature:

With dihydrogen peroxide; In water; acetonitrile; at 80 ℃; for 6h; Darkness;

DOI:10.1016/j.apcata.2010.10.026

upstream raw materials:

Cyclooctan

Downstream raw materials:

cycloactanone

cyclooctanol

Refernces

• 1、 -. "Three metal centers (Co _AOMARKENCODEAMPX0AOA) Cu _AOMARKENCODEAMPX0AOA Method using Zn) 2D MOFs/ultraviolet light to catalyze oxidation of cycloalkane". Paragraph 0028; 0079-0080. . Retrieved 2021/11/06.
• 2、 -. "Confinement porphyrin Co (II), and preparation method and application thereof". Paragraph 0103-0104. . Retrieved 2020/04/17.