potassiuM oxirane-2-carboxylate

Base Information

• Chemical Name: potassiuM oxirane-2-carboxylate
• CAS No.: 51877-54-4
• Molecular Formula: C3H4O3.K
• Molecular Weight: 126.153
• Hs Code.: 2918990090
• Mol file: 51877-54-4.mol

Synonyms:potassium,oxirane-2-carboxylate;

Chemical Property of potassiuM oxirane-2-carboxylate

Chemical Property:

• PSA: 52.66000
• LogP: -1.86490
• Storage Temp.: Inert atmosphere,Store in freezer, under -20°C

Purity/Quality:

98%min ^*data from raw suppliers

PotassiumOxirane-2-carboxylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of potassiuM oxirane-2-carboxylate

There total 5 articles about potassiuM oxirane-2-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

3-chloro-2-hydroxypropanoic acid (1713-85-5) → potassium oxirane-2-carboxylate (51877-54-4)

Guidance literature:

With potassium hydroxide; In methanol; 1) room temperature, 1 h; 2) 5 deg C, overnight;

DOI:10.1021/ja00380a021

Reference yield:

methyl glycidate (4538-50-5) → potassium oxirane-2-carboxylate (51877-54-4)

Guidance literature:

With potassium hydroxide; In methanol;

DOI:10.1021/jo00029a051

Reference yield:

(R,S)-3-bromo-2-hydroxypropanoic acid (32777-03-0) → (+)-2,3-epoxy-propionic acid ; potassium-salt (51877-54-4,52994-17-9,82044-23-3,82079-45-6)

Guidance literature:

With ethanol;

upstream raw materials:

methyl glycidate

3-chloro-2-hydroxypropanoic acid

(R,S)-3-bromo-2-hydroxypropanoic acid

d-β-bromo-lactic acid

Downstream raw materials:

2-hydroxy-3-(triphenylmethyl)thiopropanoic acid

2-hydroxy-3-(phenylthio)propionic acid

Refernces

• 1、 Bihovsky, Ron. "Reactions of α,β-Epoxy Carbonyl Compounds with Methanethiolate: Regioselectivity and Rate". . p. 1029 - 1031. Retrieved 2007/10/02.