(2-Cyclohexylideneethylidene)cyclohexane

Base Information

• Chemical Name: (2-Cyclohexylideneethylidene)cyclohexane
• CAS No.: 53723-48-1
• Molecular Formula: C14H22
• Molecular Weight: 190.329
• DSSTox Substance ID: DTXSID60510579
• Nikkaji Number: J475.525A
• Mol file: 53723-48-1.mol

Synonyms:53723-48-1;(2-cyclohexylideneethylidene)cyclohexane;DTXSID60510579;AKOS015907289;2-cyclohexylidene-ethylidene-cyclohexane;1,1'-(Ethane-1,2-diylidene)dicyclohexane

Chemical Property of (2-Cyclohexylideneethylidene)cyclohexane

Chemical Property:

• XLogP3: 4.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 190.172150702
• Heavy Atom Count: 14
• Complexity: 190

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1CCC(=CC=C2CCCCC2)CC1

Technology Process of (2-Cyclohexylideneethylidene)cyclohexane

There total 21 articles about (2-Cyclohexylideneethylidene)cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

bromomethylenecyclohexane (1121-49-9) → 1,1'-(1,2-ethanediylidene)biscyclohexane (53723-48-1)

Guidance literature:

With t-AmONa-NiCRA-bpy; In tetrahydrofuran; at 60 ℃; for 1h;

DOI:10.1016/S0040-4039(00)84838-8

Reference yield: 85.0%

1-(chloromethylene)cyclohexane (1121-50-2) → 1,1'-(1,2-ethanediylidene)biscyclohexane (53723-48-1)

Guidance literature:

With t-AmONa-NiCRA-bpy; In tetrahydrofuran; at 60 ℃; for 63h;

DOI:10.1016/S0040-4039(00)84838-8

Reference yield: 75.0%

1-[(E)-2-(1-hydroxycyclohexyl)-1-ethenyl]-1-cyclohexanol (20180-54-5) → 1,1'-(1,2-ethanediylidene)biscyclohexane (53723-48-1)

Guidance literature:

With lithium aluminium tetrahydride; titanium(III) chloride; In tetrahydrofuran; for 3h; Heating;

DOI:10.1021/ja00385a052

upstream raw materials:

Acetic acid 1-(1-benzenesulfonyl-cyclohexyl)-2-cyclohexylidene-ethyl ester

(2-cyclohexylideneethyl)diphenylphosphine oxide

cyclohexanone

methylenecyclohexane

Refernces

• 1、 Aves, Sarah. J.,O'Connell, Kieron M. G.,Pike, Kurt G.,Spring, David R.. "Synthesis of highly substituted symmetrical 1,3-dienes via organocuprate oxidation". supporting information; experimental part. p. 298 - 300. Retrieved 2012/03/10.
• 2、 Huang, Jiling,Goedken, V.,Walborsky, H. M.. "Titanium-Induced Reductive Elimination of 2-Yne-1,4-diols". . p. 4128 - 4131. Retrieved 2007/10/02.