Germyl, tributyl-

Base Information

• Chemical Name: Germyl, tributyl-
• CAS No.: 55321-84-1
• Molecular Formula: C12H27Ge
• Molecular Weight: 243.936
• Mol file: 55321-84-1.mol

Synonyms:

Chemical Property of Germyl, tributyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Germyl, tributyl-

There total 2 articles about Germyl, tributyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(trimethylsilyl)methyl radical (19469-02-4) + tributylgermanium hydride (998-39-0) → tetramethylsilane (75-76-3) + tributylgermyl radical (55321-84-1)

Guidance literature:

In benzene-d6; degassed, sealed tube; constant rates of radical chain initiation achieved by the use of 2,2'-azobis(2,4-dimethylvaleronitrile) as the thermal source of initiating radicals from Me3SiCH2Br; reaction monitored by (1)H-NMR; Kinetics;

DOI:10.1021/ja00209a045

Reference yield:

n-butyl radical (2492-36-6) + tributylgermanium hydride (998-39-0) → tributylgermyl radical (55321-84-1) + n-butane (106-97-8,9003-29-6,9021-92-5)

Guidance literature:

In benzene-d6; degassed, sealed tube; constant rates of radical chain initiation achieved by the use of 2,2'-azobis(2,4-dimethylvaleronitrile) as the thermal source of initiating radicals from Me3SiCH2Br; reaction monitored by (1)H-NMR; Kinetics;

DOI:10.1021/ja00209a045

Reference yield:

1-bromo-butane (109-65-9) + tributylgermyl radical (55321-84-1) → n-butyl radical (2492-36-6) + tri-n-butylgermanium bromide (2117-37-5)

Guidance literature:

In benzene-d6; reaction studied by (1)H-NMR; Kinetics;

DOI:10.1021/ja00209a045

upstream raw materials:

n-butyl radical

tributylgermanium hydride

(trimethylsilyl)methyl radical

Downstream raw materials:

n-butyl radical

tri-n-butylgermanium bromide

(trimethylsilyl)methyl radical

Trimethylethylsilanradikal

Refernces