2,4,6-trip-tolyl-1,3,5-triazine

Base Information

• Chemical Name: 2,4,6-trip-tolyl-1,3,5-triazine
• CAS No.: 6726-45-0
• Molecular Formula: C24H21N3
• Molecular Weight: 351.451
• Mol file: 6726-45-0.mol

Synonyms:2,4,6-TRI-TOLYL-1,3,5-TRIAZINE;4,4',4''-s-triazine-2,4,6-tri-p-tolyl;2,4,6-tri-p-tolyl-s-triazine;

Chemical Property of 2,4,6-trip-tolyl-1,3,5-triazine

Chemical Property:

• Vapor Pressure: 4.66E-12mmHg at 25°C
• Melting Point: 275-276 °C
• Boiling Point: 561.5°Cat760mmHg
• PKA: 1.51±0.10(Predicted)
• Flash Point: 246.9°C
• PSA: 38.67000
• Density: 1.12g/cm³
• LogP: 5.79780

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tris(p-tolyl)-1,3,5-triazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Tris(p-tolyl)-1,3,5-triazine is an intermediate in synthesizing p-Cyanobenzoic Acid Trimer (C955200), which is used in the synthetic preparation of Terbium Triazinetribenzoate Formate Metal Organic Framework (MOF).

Technology Process of 2,4,6-trip-tolyl-1,3,5-triazine

There total 20 articles about 2,4,6-trip-tolyl-1,3,5-triazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

2,4,6-tris(phenyltelluro)-1,3,5-triazine (142312-17-2) + para-methylphenylmagnesium bromide (4294-57-9) → 2,4,6-tris(p-tolyl)-1,3,5-triazine (6726-45-0)

Guidance literature:

With bis(triphenylphosphine)nickel(II) chloride; In tetrahydrofuran; for 8h; Heating;

DOI:10.3987/COM-91-5926

Reference yield: 96.0%

para-methylbenzonitrile (104-85-8) → 2,4,6-tris(p-tolyl)-1,3,5-triazine (6726-45-0)

Guidance literature:

With [(SiMe₃)2CSiMe₂NMe₂]Li(TMEDA); In hexane;

DOI:10.3987/COM-05-10357

Reference yield: 86.0%

4-Methylbenzyl alcohol (589-18-4) + p-methylbenzamidine hydrochloride (6326-27-8) → 2,4,6-tris(p-tolyl)-1,3,5-triazine (6726-45-0)

Guidance literature:

With oxygen; copper(II) acetate monohydrate; sodium carbonate; In toluene; at 110 ℃; for 24h;

DOI:10.1039/c5ob00724k

upstream raw materials:

1,3,5-trichloro-2,4,6-triazine

toluene

cyanuric bromide

4-methyl-benzimidic acid ethyl ester

Downstream raw materials:

terephthalic acid

p-Toluic acid

[OsH₂(2,4,6-tris(4-methylphenyl)-1,3,5-triazine(-2H))(P(iPr)3)2]

(4-(4,6-di-p-tolyl-1,3,5-triazin-2-yl)benzyl)dimethylphosphineoxide

Refernces

• 1、 Chen, Xiao,Guan, Dehui,Qiao, Guan-Yu,Qin, Jun-Sheng,Rao, Heng,Wang, Jia-Ao,Xu, Ji-Jing,Yu, Jihong,Yuan, Shuai. "Perovskite Quantum Dots Encapsulated in a Mesoporous Metal-Organic Framework as Synergistic Photocathode Materials". supporting information. p. 14253 - 14260. Retrieved 2021/09/13.
• 2、 Chen, Yong,He, Yanyan,Liu, Fulai,Liu, Honglai,Ma, Wangping,Yang, Na,Zhu, Xiang. "Efficient synthesis of vinylene-linked conjugated porous networksviathe Horner-Wadsworth-Emmons reaction for photocatalytic hydrogen evolution". supporting information. p. 7557 - 7560. Retrieved 2021/08/05.