Chlorodihexylaluminium

Base Information

• Chemical Name: Chlorodihexylaluminium
• CAS No.: 2674-15-9
• Molecular Formula: C12H26 Al Cl
• Molecular Weight: 232.773
• Hs Code.: 2903199000
• Mol file: 2674-15-9.mol

Synonyms:Chlorodihexylaluminium;SCHEMBL392768;EINECS 220-220-2

Chemical Property of Chlorodihexylaluminium

Chemical Property:

• Vapor Pressure: 151mmHg at 25°C
• Boiling Point: 68.5°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.14310
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 232.1538419
• Heavy Atom Count: 14
• Complexity: 71.2

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCC[Al+]CCCCCC.[Cl-]

Technology Process of Chlorodihexylaluminium

There total 5 articles about Chlorodihexylaluminium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-hexene (592-41-6,25067-06-5) + diethylaluminium chloride (96-10-6) → 2-ethyl-1-hexene (1632-16-2) + di(n-hexyl)aluminum chloride (2674-15-9)

Guidance literature:

With zirconium (IV) butoxide; In toluene; at 20 ℃; for 4h; further catalysts;

DOI:10.1007/BF00953581

Reference yield: 95.0%

1-hexene (592-41-6,25067-06-5) + diethylaluminium chloride (96-10-6) → 2-ethyl-1-hexene (1632-16-2) + di(n-hexyl)aluminum chloride (2674-15-9) + ethyl(n-hexyl)aluminium chloride

Guidance literature:

With zirconium (IV) butoxide; In toluene; at 20 ℃; for 4h; Product distribution; Mechanism; further catalysts (Ti(OBu)4, Hf(OBu)4, ZrCl₄, TiCl₄, (C₅H₅N)2ZrCl₂); effect of educt ratio;

DOI:10.1007/BF00953581

Reference yield: 75.0%

1-hexene (592-41-6,25067-06-5) + di-n-propylaluminum chloride (3710-19-8) → 4-methyleneoctane (62187-09-1) + di(n-hexyl)aluminum chloride (2674-15-9)

Guidance literature:

With zirconium (IV) butoxide; In toluene; at 50 ℃; for 4h;

DOI:10.1007/BF00953581

upstream raw materials:

1-hexene

di-n-propylaluminum chloride

diethylaluminium chloride

Downstream raw materials:

non-1-ene

hexane

1-methoxyheptane

trihexylaluminium

Refernces