Benzenamine, N-phenyl-, lithium salt

Base Information

• Chemical Name: Benzenamine, N-phenyl-, lithium salt
• CAS No.: 5856-89-3
• Molecular Formula: C12H11N.Li
• Molecular Weight: 175.159
• Mol file: 5856-89-3.mol

Synonyms:

Chemical Property of Benzenamine, N-phenyl-, lithium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenamine, N-phenyl-, lithium salt

There total 4 articles about Benzenamine, N-phenyl-, lithium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.5%

diphenylamine (122-39-4) → lithium diphenylamide (5856-89-3)

Guidance literature:

With ethyllithium; In diethyl ether; hexane; at 0 ℃; for 1.5h;

DOI:10.1021/ja00224a041

Reference yield:

lithium amide + N-nitrosodiphenylamine (382165-80-2,86-30-6) → lithium diphenylamide (5856-89-3) + lithium hydroxide (1310-65-2)

Guidance literature:

In ammonia; byproducts: N2;

DOI:10.1021/ja01335a082

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + diphenylamine (122-39-4) → lithium diphenylamide (5856-89-3)

Guidance literature:

In tetrahydrofuran; hexane; at -78 - 20 ℃; for 0.5h;

DOI:10.1021/ja011110o

upstream raw materials:

diphenylamine

n-butyllithium

N-nitrosodiphenylamine

Downstream raw materials:

N,N-diphenylaminobenzene

oct-1-ene

N-octyl-N-phenylaniline

N-butyl-N-phenylbenzenamine

Refernces

• 1、 Bole, Leonie J.,Fairley, Michael,García-Alvarez, Joaquín,Hevia, Eva,Kennedy, Alan R.,Main, Laura,Mulks, Florian F.,O'Hara, Charles T.. "Ultrafast amidation of esters using lithium amides under aerobic ambient temperature conditions in sustainable solvents". . p. 6500 - 6509. Retrieved 2020/07/15.
• 2、 Hatakeyama, Takuji,Imayoshi, Ryuji,Yoshimoto, Yuya,Ghorai, Sujit K.,Jin, Masayoshi,Takaya, Hikaru,Norisuye, Kazuhiro,Sohrin, Yoshiki,Nakamura, Masaharu. "Iron-catalyzed aromatic amination for nonsymmetrical triarylamine synthesis". supporting information. p. 20262 - 20265. Retrieved 2013/02/23.