Benzenethiol, 2-(1H-benzimidazol-2-yl)-

Base Information

• Chemical Name: Benzenethiol, 2-(1H-benzimidazol-2-yl)-
• CAS No.: 5918-45-6
• Molecular Formula: C₁₃H₁₀N₂S
• Molecular Weight: 226.302
• Mol file: 5918-45-6.mol

Synonyms:

Chemical Property of Benzenethiol, 2-(1H-benzimidazol-2-yl)-

Chemical Property:

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenethiol, 2-(1H-benzimidazol-2-yl)-

There total 1 articles about Benzenethiol, 2-(1H-benzimidazol-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

Thiosalicylic acid (147-93-3) + 1,2-diamino-benzene (95-54-5) → 2-(1H-benzimidazol-2-yl)benzenethiol (5918-45-6)

Guidance literature:

With phosphorus trichloride; In toluene; for 4h; Inert atmosphere; Reflux;

DOI:10.1039/c9ra03199e

Reference yield:

bis(triphenylphosphineiminium) dichloronitrosyliron (61045-72-5) + 2-(1H-benzimidazol-2-yl)benzenethiol (5918-45-6) → C13H8FeN4O2S(1-)*C36H30NP2(1+)

Guidance literature:

2-(1H-benzimidazol-2-yl)benzenethiol; With potassium hydride; In tetrahydrofuran; at 20 ℃;

bis(triphenylphosphineiminium) dichloronitrosyliron; In tetrahydrofuran; at -35 - 20 ℃; for 2h;

DOI:10.1021/acs.inorgchem.8b02927

upstream raw materials:

Thiosalicylic acid

1,2-diamino-benzene

Refernces

• 1、 Bossio, Ricardo,Marcaccini, Stefano,Parrini, Valerio,Pepino, Roberto. "SYNTHESIS OF NOVEL RING SYSTEM: PYRIDOISOTHIAZOLOBENZIMIDAZOLE". . p. 2705 - 2708. Retrieved 2007/10/02.