dipotassium cyclooctatetraene

Base Information

• Chemical Name: dipotassium cyclooctatetraene
• CAS No.: 59391-85-4
• Molecular Formula: C₈H₈*2K
• Molecular Weight: 182.348
• Mol file: 59391-85-4.mol

Synonyms:

Chemical Property of dipotassium cyclooctatetraene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dipotassium cyclooctatetraene

There total 4 articles about dipotassium cyclooctatetraene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium graphite + uranocene (11079-26-8) → potassium salt of the COT dianion (59391-85-4)

Guidance literature:

uranocene; With [2,2]bipyridinyl; In tetrahydrofuran-d8; at 90 ℃; for 1h; Inert atmosphere;

potassium graphite; In tetrahydrofuran-d8; at 90 ℃; for 1h; Inert atmosphere;

DOI:10.1016/j.crci.2013.09.006

Reference yield:

1,3,5,7-cyclooctatetraene (629-20-9) → 2K*C8H8=K2C8H8 (59391-85-4)

Guidance literature:

With potassium; In tetrahydrofuran;

Reference yield:

1,3,5,7-cyclooctatetraene (629-20-9) → potassium salt of the COT dianion (59391-85-4)

Guidance literature:

With potassium; In tetrahydrofuran; Thermodynamic data; involving THF solution of product;

DOI:10.1021/j150666a062

upstream raw materials:

1,3,5,7-cyclooctatetraene

(1Z,3Z,5Z)-Cycloocta-1,3,5-triene

uranocene

Refernces

• 1、 Calderazzo, Fausto,Marchetti, Fabio,Pampaloni, Guido,Hiller, Wolfgang,Antropiusova, Helena,Mach, Karel. "Reactivity of Titanium(II) Arene Derivatives with Substituted Alkynes. Cyclooligomerization Reactions and Crystal and Molecular Structure of 4-C4(C6H5)4>Ti2". . p. 2229 - 2238. Retrieved 2007/10/02.