Octane, 1-bromo-3,7-dimethyl-, (3R)-

Base Information

• Chemical Name: Octane, 1-bromo-3,7-dimethyl-, (3R)-
• CAS No.: 59965-20-7
• Molecular Formula: C10H21Br
• Molecular Weight: 221.181
• Mol file: 59965-20-7.mol

Synonyms:

Chemical Property of Octane, 1-bromo-3,7-dimethyl-, (3R)-

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Octane, 1-bromo-3,7-dimethyl-, (3R)-

There total 10 articles about Octane, 1-bromo-3,7-dimethyl-, (3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

tetrahydrogeraniol (106-21-8,59204-02-3) → 1-bromo-3,7-dimethyloctane (59965-20-7,72746-96-4,79434-89-2,3383-83-3)

Guidance literature:

With sulfuric acid; hydrogen bromide; In water; at 120 - 125 ℃; for 3h;

Reference yield: 100.0%

(S)-citronellyl bromide (10340-84-8,4895-14-1,58800-75-2,143615-81-0) → (S)-1-bromo-3,7-dimethyloctane (3383-83-3,59965-20-7,72746-96-4,79434-89-2)

Guidance literature:

With platinum(IV) oxide; hydrogen; In ethyl acetate; for 24h; under 60006 Torr;

DOI:10.1002/anie.201000580

Reference yield: 95.1%

→ 1-bromo-3,7-dimethyloctane (59965-20-7,72746-96-4,79434-89-2,3383-83-3)

Guidance literature:

With sulfuric acid; In hydrogen bromide; liquid HBr;

upstream raw materials:

tetrahydrogeraniol

Citronellol

Geraniol

S-(-)-dihydrocitronellol

Downstream raw materials:

3,7-dimethyl-oct-1-ene

5,9-Dimethyl-2-(toluene-4-sulfonyl)-decanoic acid methyl ester

2-(3,7-Dimethyl-octyl)-5,9-dimethyl-2-(toluene-4-sulfonyl)-decanoic acid methyl ester

5,9-Dimethyl-2-(toluene-4-sulfonyl)-decanoic acid tert-butyl ester

Refernces

• 1、 Nelson, Zachary,Delage-Laurin, Leo,Peeks, Martin D.,Swager, Timothy M.. "Large Faraday Rotation in Optical-Quality Phthalocyanine and Porphyrin Thin Films". supporting information. p. 7096 - 7103. Retrieved 2021/05/29.
• 2、 Ahlatc?o?lu ?zerol, Esma,Ocak, Hale,Bilgin Eran, Belk?z,Karavelio?lu, Selvi. "The synthesis and dielectric properties of a new phenylbenzoate-based calamitic liquid crystal". . p. 225 - 232. Retrieved 2020/08/10.