(3R)-3,7-Dimethyl-1-octanone

Base Information

• Chemical Name: (3R)-3,7-Dimethyl-1-octanone
• CAS No.: 60018-13-5
• Molecular Formula: C10H20O
• Molecular Weight: 156.268
• Mol file: 60018-13-5.mol

Synonyms:R-tetrahydrocitral;dihydrocitronellal;R-3,7-dimethyloctanal;(R)-3,7-dimethyloctanal;(R)-3,7-Dimethyl-octanal;(3R)-3,7-dimethyloctanal;

Chemical Property of (3R)-3,7-Dimethyl-1-octanone

Chemical Property:

• Boiling Point: 31-33 °C(Press: 0.15 Torr)
• PSA: 17.07000
• Density: 0.815±0.06 g/cm3(Predicted)
• LogP: 3.03780

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (3R)-3,7-Dimethyl-1-octanone

There total 64 articles about (3R)-3,7-Dimethyl-1-octanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

3,7-dimethyl-oct-6-enal (106-23-0,26489-02-1) → 3,7-dimethyl-1-octanal (60018-13-5,81738-03-6,124440-53-5,25795-46-4,5988-91-0)

Guidance literature:

With 5%-palladium/activated carbon; hydrogen; In ethyl acetate; at 20 ℃; for 2h;

DOI:10.1002/pola.24737

Reference yield: 96.0%

tetrahydrogeraniol (106-21-8,59204-02-3) → 3,7-dimethyl-1-octanal (60018-13-5,81738-03-6,124440-53-5,25795-46-4,5988-91-0)

Guidance literature:

With sodium hypochlorite; sodium hydrogencarbonate; potassium bromide; heterogenous polymeric TEMPO on Pt; In dichloromethane; at 0 ℃; for 1h; pH=9.1;

DOI:10.1021/ja002334u

Reference yield: 86.0%

(E/Z)-3,7-dimethyl-2,6-octadienal (5392-40-5,96680-15-8) → 3,7-dimethyl-1-octanal (60018-13-5,81738-03-6,124440-53-5,25795-46-4,5988-91-0)

Guidance literature:

With hydrogen; In ethanol; at 20 ℃; for 3h; under 760.051 Torr; chemoselective reaction;

DOI:10.1039/c1gc15217c

upstream raw materials:

(E/Z)-3,7-dimethyl-2,6-octadienal

3,7-dimethylocta-2,4,6-trienal

3,7-dimethyl-2-octenal

Citronellol

Downstream raw materials:

5-(3,7-Dimethyl-octyl)-3-methylsulfanyl-1,4-diphenyl-4H-[1,2,4]triazol-1-ium; iodide

Ethyl-3,7,11-Trimethyl-cis-2,trans-4-dodecadienoat

hydroprene

(S)-hydroprene

Refernces

• 1、 Ardiansah, Bayu,Kakiuchi, Kiyomi,Morimoto, Tsumoru,Tanimoto, Hiroki,Tomohiro, Takenori. "Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides". . p. 8738 - 8741. Retrieved 2021/09/08.
• 2、 An, Rui,Li, Huimin,Liao, Lihao,Wu, Jin-Ji,Xu, Yang,Zhao, Xiaodan. "Catalytic Access to Functionalized Allylic gem-Difluorides via Fluorinative Meyer–Schuster-Like Rearrangement". supporting information. p. 11010 - 11019. Retrieved 2020/05/18.