9-(4-Vinylbenzyl)-9H-carbazole

Base Information

• Chemical Name: 9-(4-Vinylbenzyl)-9H-carbazole
• CAS No.: 60181-05-7
• Molecular Formula: C21H17N
• Molecular Weight: 283.373
• DSSTox Substance ID: DTXSID90596043
• Nikkaji Number: J1.513.110A
• Wikidata: Q82491171
• Mol file: 60181-05-7.mol

Synonyms:60181-05-7;9-(4-Vinylbenzyl)-9H-carbazole;SCHEMBL955942;4-(9-carbazolyl)methylstyrene;DTXSID90596043;9-(4-Ethenylbenzyl)-9H-Carbazole;9-[(4-ETHENYLPHENYL)METHYL]-9H-CARBAZOLE

Chemical Property of 9-(4-Vinylbenzyl)-9H-carbazole

Chemical Property:

• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 283.136099547
• Heavy Atom Count: 22
• Complexity: 359

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC1=CC=C(C=C1)CN2C3=CC=CC=C3C4=CC=CC=C42

Technology Process of 9-(4-Vinylbenzyl)-9H-carbazole

There total 2 articles about 9-(4-Vinylbenzyl)-9H-carbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4-Vinylbenzyl chloride (1592-20-7,29296-32-0) + 9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 4-(9-carbazolyl)methyl styrene (60181-05-7)

Guidance literature:

With sodium hydroxide; In N,N-dimethyl-formamide; at 20 ℃; for 24h;

DOI:10.1016/j.polymer.2010.03.001

Reference yield:

→ 4-(9-carbazolyl)methyl styrene (60181-05-7)

Guidance literature:

Carbazol, m-, p-Vinylbenzylchlorid-Gemisch (4, 5);

DOI:10.1021/ma60057a020

Reference yield: 90.0%

4-(9-carbazolyl)methyl styrene (60181-05-7) → 9-[4-(vinyl-d3)benzyl]-9H-carbazole

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; (S)-Mandelic acid; water-d2; tricyclohexylphosphine; In toluene; at 120 ℃; for 16h; Inert atmosphere;

DOI:10.1055/s-0039-1690892

upstream raw materials:

4-Vinylbenzyl chloride

9H-carbazole

Refernces

• 1、 Gulfidan, Damla,Sefer, Emre,Koyuncu, Sermet,Acar, Metin H.. "Neutral state colorless electrochromic polymer networks: Spacer effect on electrochromic performance". . p. 5998 - 6005. Retrieved 2015/01/09.
• 2、 Tao, Yongxin,Xu, Qingfeng,Li, Najun,Lu, Jianmei,Wang, Lihua,Xia, Xuewei. "Synthesis and photoluminescent property of star polymers with carbzole pendent and a zinc porphyrin core by ATRP". . p. 4261 - 4267,7. Retrieved 2012/12/12.