1,1'-ONN-Azoxybisnaphthalene

Base Information

• Chemical Name: 1,1'-ONN-Azoxybisnaphthalene
• CAS No.: 605-84-5
• Molecular Formula: C₂₀H₁₄N₂O
• Molecular Weight: 298.344
• Mol file: 605-84-5.mol

Synonyms:di-1-naphthalenyl-diazene,1-oxide;[1.1']Azoxynaphthalin;Diazene, di-1-naphthalenyl-, 1-oxide;α.α'-Azoxynaphthalin;Di-[1]naphthyl-diazen-N-oxid;

Chemical Property of 1,1'-ONN-Azoxybisnaphthalene

Chemical Property:

• PSA: 41.11000
• LogP: 6.44190

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,1'-ONN-Azoxybisnaphthalene

There total 5 articles about 1,1'-ONN-Azoxybisnaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

1-Nitronaphthalene (86-57-7) → 1-amino-naphthalene (134-32-7) + 1,2-di(naphthalen-1-yl)diazene (487-10-5) + di-1-naphthalenyl-diazene, 1-oxide (605-84-5,104124-90-5)

Guidance literature:

With hydrazine hydrate; nickel(II) nitrate; zinc; In tert-butyl alcohol; for 0.833333h; Heating;

Reference yield: 33.0%

1-Nitronaphthalene (86-57-7) → 1,2-di(naphthalen-1-yl)diazene (487-10-5) + di-1-naphthalenyl-diazene, 1-oxide (605-84-5,104124-90-5)

Guidance literature:

With water; ammonium chloride; zinc; In N,N-dimethyl-formamide; at 80 ℃; for 1h; Further Variations:; Temperatures; time, irradiation; Product distribution; microwave irradiation;

DOI:10.1055/s-2006-951481

Reference yield:

1-Nitronaphthalene (86-57-7) → (Z)-1,2-di(naphthalen-1-yl)diazene 1-oxide (605-84-5,104124-90-5) + 1-amino-naphthalene (134-32-7)

Guidance literature:

With pyridine; hydrogen sulfide;

upstream raw materials:

1-Nitronaphthalene

diphenyl hydrazine

ethanol

Downstream raw materials:

1-(2'-hydroxynaphthylazo)naphthalene

(E)-1-(2-(naphthalen-1-yl)diazen-1-yl)naphthalen-2-ol

4,4'-diamino-1,1'-binaphthyl

Refernces

• 1、 Yun, Tae Ho,Park, Moon Keu,Han, Byung Hee. "Reduction of Nitroarenes Using an Activated Catalyst Prepared by the Reduction of Nickel Nitrate with Excess Zinc in the Presence of Hydrazine Monohydrate". . p. 2774 - 2788. Retrieved 2007/10/02.