Zinc, bromoethyl-

Base Information

• Chemical Name: Zinc, bromoethyl-
• CAS No.: 6107-37-5
• Molecular Formula: C2H5BrZn
• Molecular Weight: 174.356
• Mol file: 6107-37-5.mol

Synonyms:

Chemical Property of Zinc, bromoethyl-

Chemical Property:

• Melting Point: 81 °C

Purity/Quality:

98% ^*data from raw suppliers

Ethylzincbromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Zinc, bromoethyl-

There total 5 articles about Zinc, bromoethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

ethyl bromide (74-96-4) + zinc (7440-66-6) → ethylzinc bromide (6107-37-5)

Guidance literature:

With copper(l) iodide; water; at 38 - 40 ℃; for 3.6h; Reagent/catalyst; Time; Concentration; Kinetics;

DOI:10.1134/S1070363216020080

Reference yield:

ethylmagnesium bromide (925-90-6) → ethylzinc bromide (6107-37-5)

Guidance literature:

With zinc dibromide; In tetrahydrofuran;

Reference yield:

zinc dibromide (7699-45-8) → ethylzinc bromide (6107-37-5)

Guidance literature:

In tetrahydrofuran; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1055/s-0036-1591488

upstream raw materials:

ethylmagnesium bromide

diethylzinc

zinc dibromide

ethyl bromide

Downstream raw materials:

(4aS,5R,9bS)-5-(4-carbomethoxyphenyl)-2-ethyl-8-ethynyl-2,3,4,4a,5,9b-hexahydro-7-methyl-1H-indeno[1,2-c]-pyridine

2-ethylpyridine-4-carboxamide

2-ethylnaphthalene

pentylbenzene

Refernces

• 1、 Taillemaud, Sylvain,Charette, André B.. "Spectroscopic Characterization of Heterohalogenic Dihalomethylzinc Carbenoids: Application to a More Efficient Chlorocyclopropanation Reaction". supporting information. p. 83 - 92. Retrieved 2022/01/04.
• 2、 Cochran, Brian M.,Henderson, Daniel D.,Thullen, Scott M.,Rovis, Tomislav. "Rhodium-Catalyzed Desymmetrization of meso -Glutaric Anhydrides to Access Enantioenriched anti, anti -Polypropionates". supporting information. p. 306 - 309. Retrieved 2017/10/26.