Chloro-methyl-(4-methylphenyl)silicon

Base Information

• Chemical Name: Chloro-methyl-(4-methylphenyl)silicon
• CAS No.: 26495-31-8
• Molecular Formula: C8H11 Cl Si
• Molecular Weight: 169.7035
• NSC Number: 170009
• DSSTox Substance ID: DTXSID80422640
• Wikidata: Q82234606
• Mol file: 26495-31-8.mol

Synonyms:26495-31-8;chloro-methyl-(4-methylphenyl)silicon;NSC170009;DTXSID80422640;NSC-170009

Chemical Property of Chloro-methyl-(4-methylphenyl)silicon

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 169.0240295
• Heavy Atom Count: 10
• Complexity: 97.4

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)[Si](C)Cl

Technology Process of Chloro-methyl-(4-methylphenyl)silicon

There total 2 articles about Chloro-methyl-(4-methylphenyl)silicon which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dichloromethylsilane (75-54-7) + para-bromotoluene (106-38-7) → 4-(Chlor-methyl-silyl)-toluol (26495-31-8)

Guidance literature:

para-bromotoluene; In tetrahydrofuran; Inert atmosphere;

Dichloromethylsilane; In tetrahydrofuran; Inert atmosphere; Cooling;

DOI:10.1021/jacs.0c04533

Reference yield:

→ 4-(Chlor-methyl-silyl)-toluol (26495-31-8)

Guidance literature:

Dichlor-methyl-silan in Ae., p-Tolylmagnesiumbromid;

Reference yield: 76.0%

[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]dimethylsilanol (299412-14-9) + 4-(Chlor-methyl-silyl)-toluol (26495-31-8) → 1-[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]-1,1,3-trimethyl-3-(p-tolyl)disiloxane (506406-52-6)

Guidance literature:

With Et₃N; In diethyl ether; byproducts: [Et3NH]Cl; under N2, stirring at room temp. in the dark for 24 h; residue was suspended in n-pentane, mixt. was filtered, filtrate was concd. in vac., drying at 5E-5 Torr for 6 h, elem. anal.;

DOI:10.1002/1099-0682(200212)2002:12<3242::AID-EJIC3242>3.0.CO;2-Q

upstream raw materials:

Dichloromethylsilane

para-bromotoluene

Downstream raw materials:

trisyl(p-methylphenyl)methylsilane

1-{[(Methoxy-dimethyl-silanyl)-bis-trimethylsilanyl-methyl]-dimethyl-silanyl}-4-methyl-benzene

1-[[dicarbonyl(η(5)-cyclopentadienyl)ferrio]methyl]-1,1,3-trimethyl-3-(p-tolyl)disiloxane

1-[dicarbonyl(η(5)-cyclopentadienyl)ferrio]-1,1,3-trimethyl-3-(4-methylphenyl)disiloxane

Refernces