Chlorodimethyl(3-phenylpropyl)silane

Base Information

• Chemical Name: Chlorodimethyl(3-phenylpropyl)silane
• CAS No.: 17146-09-7
• Molecular Formula: C11H17ClSi
• Molecular Weight: 212.794
• Hs Code.: 2931900090
• European Community (EC) Number: 241-208-3
• UNII: F68VRD387A
• DSSTox Substance ID: DTXSID0066167
• Nikkaji Number: J307.696B
• Wikidata: Q81992746
• Mol file: 17146-09-7.mol

Synonyms:Chlorodimethyl(3-phenylpropyl)silane;17146-09-7;(3-Phenylpropyl)dimethylchlorosilane;3-Phenylpropyldimethylchlorosilane;chloro-dimethyl-(3-phenylpropyl)silane;Silane, chlorodimethyl(3-phenylpropyl)-;Benzene, (3-(chlorodimethylsilyl)propyl)-;F68VRD387A;EINECS 241-208-3;C11H17ClSi;UNII-F68VRD387A;C11-H17-Cl-Si;SCHEMBL523288;DTXSID0066167;(3-phenylpropyl) dimethylchlorosilane;(3-phenylpropyl)dimethyl-chlorosilane;MFCD00049281;AKOS015848700;ISOQUINOLINE-3-YLDIPHENYLMETHANOL;(3-PHENYLPROPYL)DIMETHYL CHLOROSILANE;C1488;FT-0637508;Chlorodimethyl(3-phenylpropyl)silane, >/=97%;D89417

Chemical Property of Chlorodimethyl(3-phenylpropyl)silane

Chemical Property:

• Vapor Pressure: 0.0186mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.489
• Boiling Point: 261.6 °C at 760 mmHg
• Flash Point: 103.8 °C
• PSA: 0.00000
• Density: 0.972 g/cm³
• LogP: 4.06310
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 212.0788048
• Heavy Atom Count: 13
• Complexity: 139

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chlorodimethyl(3-phenylpropyl)silane >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Statements: 34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(CCCC1=CC=CC=C1)Cl

Technology Process of Chlorodimethyl(3-phenylpropyl)silane

There total 4 articles about Chlorodimethyl(3-phenylpropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

allylbenzene (300-57-2,57807-91-7) + dimethylmonochlorosilane (1066-35-9) → dimethyl(3-phenylpropyl)chlorosilane (17146-09-7)

Guidance literature:

dihydrogen hexachloroplatinate; In isopropyl alcohol; at 90 ℃;

DOI:10.1007/s11176-005-0113-5

Reference yield: 65.0%

dimethylmonochlorosilane (1066-35-9) + cyclopropylbenzene (873-49-4) → dimethyl(3-phenylpropyl)chlorosilane (17146-09-7)

Guidance literature:

With aluminium trichloride; In hexane; at 20 ℃; for 2h;

DOI:10.1016/S0040-4039(01)00925-X

Reference yield:

1-Bromo-3-phenylpropane (637-59-2) + dimethylsilicon dichloride (75-78-5,30107-43-8) → dimethyl(3-phenylpropyl)chlorosilane (17146-09-7)

Guidance literature:

Multistep reaction; (i) Mg, Et₂O, (ii) /BRN= 605287/;

DOI:10.1016/S0022-328X(00)83726-2

upstream raw materials:

1-Bromo-3-phenylpropane

dimethylsilicon dichloride

dimethylmonochlorosilane

cyclopropylbenzene

Downstream raw materials:

1,3-Bis-(3-phenyl-propyl)-1,1,3,3-tetramethyl-disiloxan

3-bromo-3-phenylpropyldimethylchlorosilane

1,1-Dimethyl-2-phenyl-1-silacyclobutane

Z-1,4-bis[dimethyl(3-phenylpropyl)silyl]-2-butene

Refernces

• 1、 Yarosh,Zhilitskaya,Yarosh,Albanov,Voronkov. "2- and 3-Arylpropyl(ethynyl)dimethylsilanes". . p. 1890 - 1894. Retrieved 2007/10/03.