Technology Process of Benzenesulfonic acid, 4-methyl-,
(3-methyl-2-cyclohexen-1-ylidene)hydrazide, (Z)-
There total 1 articles about Benzenesulfonic acid, 4-methyl-,
(3-methyl-2-cyclohexen-1-ylidene)hydrazide, (Z)- which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
methanol;
at 45 ℃;
Overall yield = 89 %; Overall yield = 4.38 g;
DOI:10.1039/c8ob00435h
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.) n-butyllithium / 1.) THF, N,N,N',N'-tetramethylene diamine
2: 78 percent / sodium borohydride / acetic acid / 4 h / 70 °C
3: m-chloroperbenzoic acid / CH2Cl2 / -78 °C
4: 1.)lithium diethylamide / 1.) THF, -78 deg C; 2.) rt
5: 60 percent / HgCl2 / acetonitrile; H2O / 5 h / 70 °C
With
sodium tetrahydroborate; n-butyllithium; lithium diethylamide; 3-chloro-benzenecarboperoxoic acid; mercury dichloride;
In
dichloromethane; water; acetic acid; acetonitrile;
DOI:10.1246/cl.1981.1579
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) n-butyllithium / 1.) THF, N,N,N',N'-tetramethylene diamine
2: 78 percent / sodium borohydride / acetic acid / 4 h / 70 °C
3: m-chloroperbenzoic acid / CH2Cl2 / -78 °C
4: 71 percent / thiophenol, t-BuOK / tetrahydrofuran / 5 h / Heating
With
sodium tetrahydroborate; n-butyllithium; potassium tert-butylate; thiophenol; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane; acetic acid;
DOI:10.1246/cl.1981.1579