TEBBE REAGENT

Base Information

• Chemical Name: TEBBE REAGENT
• CAS No.: 67719-69-1
• Molecular Formula: C13H18AlClTi10*
• Molecular Weight: 284.58
• Hs Code.: 29310099
• Mol file: 67719-69-1.mol

Synonyms:TEBBE REAGENT;

Chemical Property of TEBBE REAGENT

Chemical Property:

• Flash Point: 34 °F
• PSA: 0.00000
• Density: 0.96 g/mL at 20 °C
• LogP: 4.36090
• Storage Temp.: Refrigerator
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Soluble in toluene, benzene, dichloromethane. Insoluble in water.

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tebbe reagent solution 0.5 M in toluene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,T
• Hazard Codes: F,C
• Statements: 11-34-48/20-63-65-67
• Safety Statements: 26-36/37/39-45-62-16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: Reagent for the methylenation of carbonyl groups. μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity. Tebbe reagent can be used:?????For the conversion of carbonyl groups of chlorophyll derivatives into the corresponding exo-methylene (or vinylidene) groups.In the synthesis of β-C-glycosides from 3-OH glycol esters.As a versatile methylenation reagent for the conversion of ketones and aldehydes to olefins. It offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers.To olefinate aldehydes.To methylenate a chiral polyhydroxyketone with high diasteroselctivity.