1-(2-Hydroxyethyl)-3-methylimidazolium chloride

Base Information

• Chemical Name: 1-(2-Hydroxyethyl)-3-methylimidazolium chloride
• CAS No.: 61755-34-8
• Molecular Formula: C6H11N2O.Cl
• Molecular Weight: 164.63300
• European Community (EC) Number: 695-725-8
• UNII: RH9J4D7U9R
• ChEMBL ID: CHEMBL3182480
• DSSTox Substance ID: DTXSID0047872
• Mol file: 61755-34-8.mol

Synonyms:61755-34-8;1-(2-HYDROXYETHYL)-3-METHYLIMIDAZOLIUM CHLORIDE;3-(2-hydroxyethyl)-1-methylimidazolium chloride;3-(2-hydroxyethyl)-1-methyl-1H-imidazol-3-ium chloride;DTXSID0047872;2-(3-methylimidazol-3-ium-1-yl)ethanol;chloride;1-(2 inverted exclamation mark -hydroxylethyl)-3-methylimidazolium chloride;RH9J4D7U9R;1-(2'-hydroxylethyl)-3-methylimidazolium chloride;SCHEMBL1048128;1-(2-hydroxyethyl)-3-methyl-1H-imidazol-3-ium chloride;CHEMBL3182480;DTXCID6027848;QVRFXIWAQRNWEX-UHFFFAOYSA-M;Tox21_200118;AC8431;MFCD11865031;MFCD12761437;ZB1673;AKOS037646217;NCGC00257672-01;AS-67349;SY036116;CAS-61755-34-8;CS-0158152;H1254;A913520;1H-Imidazolium, 3-(2-hydroxyethyl)-1-methyl-, chloride (1:1);1-(2invertedexclamationmark-hydroxylethyl)-3-methylimidazoliumchloride

Chemical Property of 1-(2-Hydroxyethyl)-3-methylimidazolium chloride

Chemical Property:

• Melting Point: 86℃
• PSA: 26.71000
• LogP: 0.33260
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 162.0559907
• Heavy Atom Count: 10
• Complexity: 87.1

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(3-Methyl-1,2-dihydroimidazol-1-ium-1-yl)ethanolChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[N+]1=CN(C=C1)CCO.[Cl-]

Technology Process of 1-(2-Hydroxyethyl)-3-methylimidazolium chloride

There total 5 articles about 1-(2-Hydroxyethyl)-3-methylimidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-methyl-1H-imidazole (616-47-7) + 2-chloro-ethanol (107-07-3) → 3-(2-hydroxyethyl)-1-methyl-1H-imidazol-3-ium chloride (61755-34-8)

Guidance literature:

at 180 ℃; for 0.166667h; microwave irradiation;

DOI:10.1016/j.tet.2005.09.118

Reference yield: 98.0%

1-methyl-1H-imidazole (616-47-7) + 3-monochloro-1,2-propanediol (96-24-2) → 3-(2-hydroxyethyl)-1-methyl-1H-imidazol-3-ium chloride (61755-34-8)

Guidance literature:

at 120 ℃; for 0.0833333h; microwave irradiation;

DOI:10.1080/00397910701749633

Reference yield: 81.0%

3-methyl-1-(2-trimethylsilyloxy)ethylimidazolium chloride (1261121-13-4) → 3-(2-hydroxyethyl)-1-methyl-1H-imidazol-3-ium chloride (61755-34-8)

Guidance literature:

With methanol; Autoclave;

DOI:10.2478/s11532-010-0071-6

upstream raw materials:

1-methyl-1H-imidazole

2-chloro-ethanol

3-monochloro-1,2-propanediol

3-methyl-1-(2-trimethylsilyloxy)ethylimidazolium chloride

Refernces

• 1、 Yang, Haijun,Liu, Yuejia,Ning, Hongli,Lei, Jianlei,Hu, Gang. "Synthesis, structure and properties of imidazolium-based energetic ionic liquids". . p. 33231 - 33240. Retrieved 2017.
• 2、 Shokouhi, Mohammad,Adibi, Mina,Jalili, Amir Hossein,Hosseini-Jenab, Masih,Mehdizadeh, Ali. "Solubility and diffusion of H2S and CO2 in the ionic liquid 1-(2-Hydroxyethyl)-3-methylimidazolium tetrafluoroborate". . p. 1663 - 1668. Retrieved 2010.
• 3、 Sun, Jian,Zhang, Suojiang,Cheng, Weiguo,Ren, Junyi. "Hydroxyl-functionalized ionic liquid: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate". . p. 3588 - 3591. Retrieved 2008.
• 4、 Branco, Luis C.,Rosa, Joao N.,Moura Ramos, Joaquim J.,Afonso, Carlos A. M.. "Preparation and characterization of new room temperature ionic liquids". . p. 3671 - 3677. Retrieved 2002.
• 5、 Chaker, Yassine,Ilikti, Hocine,Debdab, Mansour,Moumene, Taqiyeddine,Belarbi, El Habib,Wadouachi, Anne,Abbas, Ouissam,Khelifa, Brahim,Bresson, Serge. "Synthesis and characterization of 1-(hydroxyethyl)-3-methylimidazolium sulfate and chloride ionic liquids". . p. 182 - 190. Retrieved 2016.
• 6、 Kim, Ki-Sub,Park, Seung-Yeob,Choi, Sukjeong,Lee, Huen. "Vapor pressures of the 1-butyl-3-methylimidazolium bromide + water, 1-butyl-3-methylimidazolium tetrafluoroborate + water, and 1-(2-hydroxyethyl)-3- methylimidazolium tetrafluoroborate + water systems". . p. 1550 - 1553. Retrieved 2004.
• 7、 Chen, Ling,Zheng, Mingfang,Zhou, Yu,Liu, Hong,Jiang, Hualiang. "Ionic-liquid-supported total synthesis of sansalvamide A peptide". . p. 239 - 248. Retrieved 2008.
• 8、 Ananikov, Valentine P.,Egorova, Ksenia S.,Gordeev, Evgeniy G.,Posvyatenko, Alexandra V.,Seitkalieva, Marina M.,Strukova, Elena N.,Vavina, Anna V.. "Merging structural frameworks of imidazolium, pyridinium, and cholinium ionic liquids with cinnamic acid to tune solution state behavior and properties". . . Retrieved 2022/03/14.
• 9、 Shoja, Seyed Mohammad Reza,Abdouss, Majid,Beigi, Ali Akbar Miran. "Synthesis and characterization of physicochemical properties of imidazolium-based ionic liquids and their application for simultaneous determination of sulfur compounds". . . Retrieved 2021/02/03.