Thiocyanic acid, 2-phenylethenyl ester, (E)-

Base Information

• Chemical Name: Thiocyanic acid, 2-phenylethenyl ester, (E)-
• CAS No.: 61807-26-9
• Molecular Formula: C9H7NS
• Molecular Weight: 161.227
• Mol file: 61807-26-9.mol

Synonyms:

Chemical Property of Thiocyanic acid, 2-phenylethenyl ester, (E)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiocyanic acid, 2-phenylethenyl ester, (E)-

There total 12 articles about Thiocyanic acid, 2-phenylethenyl ester, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

nitrostyrene (5153-67-3) + trimethylammonium thicoyanate → (E)-(2-thiocyanatovinyl)-benzene (61807-26-9)

Guidance literature:

With eosin Y disodium salt; In acetonitrile; at 20 ℃; for 8h; Solvent; Reagent/catalyst; stereoselective reaction; Catalytic behavior; Mechanism; Irradiation; Green chemistry;

DOI:10.1016/j.tetlet.2020.152505

Reference yield: 80.0%

potassium thioacyanate (333-20-0) + Cinnamic acid (621-82-9) → (E)-(2-thiocyanatovinyl)-benzene (61807-26-9)

Guidance literature:

With rose bengal; caesium carbonate; In acetonitrile; at 20 ℃; for 12h; Reagent/catalyst; Solvent; Irradiation;

DOI:10.1007/s10562-020-03414-6

Reference yield: 77.0%

(E)-3-phenylacrylic acid (140-10-3) + ammonium thiocyanate (1147550-11-5) → (E)-(2-thiocyanatovinyl)-benzene (61807-26-9)

Guidance literature:

With ammonium acetate; sodium perchlorate; sodium hydrogencarbonate; In water; acetonitrile; at 20 ℃; for 9h; Electrolysis; Green chemistry;

DOI:10.1021/acs.orglett.8b04136

upstream raw materials:

thiocyanogen

acetylene

benzene

potassium thioacyanate

Refernces

• 1、 Kapoor, Ritu,Chawla, Ruchi,Yadav, Lal Dhar S.. "Denitrative thiocyanation of β-nitrostyrenes through visible light photoredox catalysis: An easy access to (E)-vinyl thiocyanates". . . Retrieved 2020.
• 2、 Yan, Jie,Jin, Hongwei,Chen, Zhenchu. "Study on the stereoselective reactions of vinyl(phenyl)iodonium salts with sodium selenide, sodium sulfide, sodium azide and potassium thiocyanate". . p. 233 - 235. Retrieved 2008/02/10.