Carbon monosulfide

Base Information

• Chemical Name: Carbon monosulfide
• CAS No.: 2944-05-0
• Molecular Formula: CS
• Molecular Weight: 44.077
• DSSTox Substance ID: DTXSID00183645
• Nikkaji Number: J1.984.566D
• Wikipedia: Carbon_monosulfide
• Wikidata: Q2709182
• Metabolomics Workbench ID: 54146
• Mol file: 2944-05-0.mol

Synonyms:carbon monosulfide;carbon monosulphide;carbon sulfide

Chemical Property of Carbon monosulfide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.72950
• XLogP3: 1.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 43.97207117
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[S+]

Technology Process of Carbon monosulfide

There total 52 articles about Carbon monosulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 0.24%

carbon disulfide (75-15-0,12122-00-8) → carbon monosulfide (2944-05-0,767590-23-8)

Guidance literature:

CS-Radikals entstehen unter dem Einfluss einer elektrischen Entladung; die Bildung an Hand des Absorptionsspektrums sowie des Emissionsspektrums nachgewiesen;

DOI:10.1103/PhysRev.45.860

Reference yield:

carbon disulfide (75-15-0,12122-00-8) → carbon monosulfide (2944-05-0,767590-23-8) + sulfur (7704-34-9)

Guidance literature:

In gas; Irradiation (UV/VIS); photofragmentation (193 nm); time-of-flight mass spectrometric study;

DOI:10.1063/1.454144

Reference yield:

carbon monoxide (201230-82-2) + sulfur dioxide (7446-09-5,12143-17-8,89125-89-3) → disulfur (23550-45-0,12597-02-3) + carbon oxide sulfide (463-58-1) + carbon monosulfide (2944-05-0,767590-23-8)

Guidance literature:

In neat (no solvent); byproducts: CO2; equilibrium react., partial decompn. of COS;; small amount of CS obtained;;

DOI:10.1021/ja02174a002

upstream raw materials:

carbon disulfide

carbon oxide sulfide

thiophene

5-methylsulfanyl-4-phenyl-[1,2]dithiole-3-thione

Downstream raw materials:

Bis-(butylthio)methan

tris(butylsulfanyl)methane

N-(1,1,3,3-tetramethylbutyl)thioformamide

di-tert-butylthioketene

Refernces

• 1、 Steeves, Adam H.,Bechtel, Hans A.,Coy, Stephen L.,Field, Robert W.. "Millimeter-wave-detected, millimeter-wave optical polarization spectroscopy". . . Retrieved 2005.
• 2、 Smith, D.,Adams, N. G.. "The proton Affinity of CS". . p. 3964 - 3965. Retrieved 1985.
• 3、 Tzeng, W.-B.,Yin, H.-M.,Leung, W.-Y.,Luo, J.-Y.,Nourbakhsh, S.,et al.. "A 193 nm laser photofragmentation time-of-flight mass spectrometric study of CS2 and CS2 clusters". . p. 1658 - 1669. Retrieved 1988.
• 4、 Rincon, Marina E.,Pearson, John,Bowers, Michael T.. "Mechanism and Product Energy Disposal in the Reaction of Ar(1+)(2P3/2) with CS2(X1Σg(+)". . p. 4290 - 4294. Retrieved 1988.
• 5、 Zmolek,Sohn,Gantzel,Trogler. "Photopolymerization of liquid carbon disulfide produces nanoscale polythiene films". . p. 1199 - 1207. Retrieved 2001.
• 6、 McCrary, V. R.,Lu, R.,Zakheim, D.,Russell, J. A.,Halpern, J. B.,Jackson, W. M.. "Coaxial measurement of the translational energy distribution of CS produced In the laser photolysis of CS2 at 193 nm". . p. 3481 - 3490. Retrieved 1985.
• 7、 Dyne,Ramsay. "". . p. 1055. Retrieved 1952.
• 8、 Coppens, P.,Drowart, J.. "Mass spectrometric study of the photoionization of CS. The dissociationenergy of the CS molecule". . p. 108 - 113. Retrieved 1995.
• 9、 Rostkowska, Hanna,Lapinski, Leszek,Nowak, Maciej J.. "UV-induced transformations of matrix-isolated 1,3,4-thiadiazole-2-thiones". experimental part. p. 56 - 66. Retrieved 2010/07/08.