Butanethioamide, 2,2,3,3,4,4,4-heptafluoro-N-phenyl-

Base Information

• Chemical Name: Butanethioamide, 2,2,3,3,4,4,4-heptafluoro-N-phenyl-
• CAS No.: 61881-12-7
• Molecular Formula: C10H6F7NS
• Molecular Weight: 305.219
• Mol file: 61881-12-7.mol

Synonyms:

Chemical Property of Butanethioamide, 2,2,3,3,4,4,4-heptafluoro-N-phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Butanethioamide, 2,2,3,3,4,4,4-heptafluoro-N-phenyl-

There total 3 articles about Butanethioamide, 2,2,3,3,4,4,4-heptafluoro-N-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-(perfluorobutyl)-N-phenylhydroxylamine → 2,2,3,3,4,4,4-heptafluoro-N-phenylbutanethioamide (61881-12-7)

Guidance literature:

With potassium thioacetate; In dichloromethane; water; ethyl acetate; at 20 ℃; for 16h;

DOI:10.1021/acs.orglett.0c00768

Reference yield:

Nitrosobenzene (586-96-9) → 2,2,3,3,4,4,4-heptafluoro-N-phenylbutanethioamide (61881-12-7)

Guidance literature:

Multi-step reaction with 2 steps

1: copper(II) perchlorate hexahydrate; hydroquinone; tert.-butylhydroperoxide / water; ethyl acetate / 1 h / 20 °C

2: potassium thioacetate / water; ethyl acetate; dichloromethane / 16 h / 20 °C

With tert.-butylhydroperoxide; copper(II) perchlorate hexahydrate; hydroquinone; potassium thioacetate; In dichloromethane; water; ethyl acetate;

DOI:10.1021/acs.orglett.0c00768

Reference yield:

2,2,3,3,4,4,4-heptafluoro-N-phenylbutanamide (336-61-8) → 2,2,3,3,4,4,4-heptafluoro-N-phenylbutanethioamide (61881-12-7)

Guidance literature:

With tetraphosphorus decasulfide; In pyridine;

upstream raw materials:

2,2,3,3,4,4,4-heptafluoro-N-phenylbutanamide

Nitrosobenzene

Refernces