Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis-

Base Information

• Chemical Name: Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis-
• CAS No.: 10125-18-5
• Molecular Formula: C18H22 O2
• Molecular Weight: 270.371
• European Community (EC) Number: 634-434-2
• DSSTox Substance ID: DTXSID40143809
• Nikkaji Number: J480.551H
• Wikidata: Q83007812
• Mol file: 10125-18-5.mol

Synonyms:Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis-;10125-18-5;Benzene, 1,1'-[1,6-hexanediylbis(oxy)]bis-;1,6-Diphenoxyhexan;1,6-diphenoxyhexane;SCHEMBL497029;DTXSID40143809;[(6-PHENOXYHEXYL)OXY]BENZENE;AKOS024338104

Chemical Property of Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis-

Chemical Property:

• Boiling Point: 404.9°Cat760mmHg
• Flash Point: 154.2°C
• Density: 1.022g/cm³
• XLogP3: 5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 270.161979940
• Heavy Atom Count: 20
• Complexity: 194

Purity/Quality:

98%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OCCCCCCOC2=CC=CC=C2

Technology Process of Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis-

There total 24 articles about Benzene, 1,1'-(1,6-hexanediylbis(oxy))bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1,6-bis(4-iodophenoxy)hexane → 1,6-diphenoxyhexane (10125-18-5)

Guidance literature:

With 9-N-methylamino-1-oxophenalene; potassium tert-butylate; potassium; In 1,4-dioxane; dimethyl sulfoxide; at 20 ℃; for 24h; Inert atmosphere; Glovebox;

DOI:10.1021/acs.joc.1c00573

Reference yield: 64.0%

cyclohexenone (930-68-7) + 1,6-hexanediol (629-11-8) → 1,6-diphenoxyhexane (10125-18-5)

Guidance literature:

With copper(II) choride dihydrate; oxygen; In toluene; at 80 ℃; for 18h; sealed tube;

DOI:10.1002/anie.201200698

Reference yield:

ammonia (7664-41-7) + 3-phenoxypropyl bromide (588-63-6) → propoxybenzene (622-85-5) + 1,6-diphenoxyhexane (10125-18-5) + phenol (108-95-2,27073-41-2)

Guidance literature:

DOI:10.1021/ja01370a039

upstream raw materials:

1 ,6-dibromohexane

sodium phenoxide

1-(3-iodopropoxy)benzene

((6-iodohexyl)oxy)benzene

Downstream raw materials:

1,6-dichlorohexane

1,6-bis-cyclohexyloxy-hexane

Refernces

• 1、 Ssolonina. "-". . . Retrieved 1899.
• 2、 Zhang, Ailing,Wang, Congxiao,Lai, Xiaoyu,Zhai, Xiaofang,Pang, Maofu,Tung, Chen-Ho,Wang, Wenguang. "Reactivity of the diphosphinodithio ligated nickel(0) complex toward alkyl halides and resultant nickel(i) and nickel(ii)-alkyl complexes". supporting information. p. 15757 - 15764. Retrieved 2018/11/23.