Pentachlorophenol, TMS

Base Information

• Chemical Name: Pentachlorophenol, TMS
• CAS No.: 62269-80-1
• Molecular Formula: C9H9Cl5OSi
• Molecular Weight: 338.52
• DSSTox Substance ID: DTXSID70423803
• Wikidata: Q82236098
• Mol file: 62269-80-1.mol

Synonyms:Pentachlorophenol, TMS;62269-80-1;pentachlorophenyl tms ether;DTXSID70423803;Pentachlorophenol, TMS derivative;LPEMXQKCFPLXMH-UHFFFAOYSA-N;Pentachlorophenol, trimethylsilyl ether

Chemical Property of Pentachlorophenol, TMS

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 337.883580
• Heavy Atom Count: 16
• Complexity: 231

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)(C)OC1=C(C(=C(C(=C1Cl)Cl)Cl)Cl)Cl

Technology Process of Pentachlorophenol, TMS

There total 1 articles about Pentachlorophenol, TMS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ pentachlorophenol-TMS (62269-80-1)

Guidance literature:

Me3SiI(I), C6Cl5OMe;

DOI:10.1007/BF02659549

Reference yield: 80.0%

pentachlorophenol-TMS (62269-80-1) → Pentachlorophenol (87-86-5,67471-28-7)

Guidance literature:

With nano magnetic sulfated zirconia (Fe₃O₄ at ZrO₂/SO₄^2-); In neat (no solvent); at 20 ℃; for 0.833333h; Green chemistry;

DOI:10.1080/10426507.2016.1236104

Reference yield:

pentachlorophenol-TMS (62269-80-1) → trimethylsilyl fluoride (420-56-4) + 2,3,4,5,6-pentachloro-4-(pentachlorophenoxy)-2,5-cyclohexadienone (17540-48-6)

Guidance literature:

With pyridine; iodine pentafluoride; In dichloromethane; Ambient temperature;

DOI:10.1016/S0022-1139(00)85206-9

Downstream raw materials:

trimethylsilyl fluoride

2,3,4,5,6-pentachloro-4-(pentachlorophenoxy)-2,5-cyclohexadienone

Pentachlorophenol