1-Naphthylglucoside

Base Information

• Chemical Name: 1-Naphthylglucoside
• CAS No.: 19939-82-3
• Molecular Formula: C16H18 O6
• Molecular Weight: 306.315
• Hs Code.: 2932999099
• Mol file: 19939-82-3.mol

Synonyms:1-naphthalenylglucopyranoside;1-naphthylglucoside;beta-naphthyl-beta-D-glucopyranoside

Chemical Property of 1-Naphthylglucoside

Chemical Property:

• Vapor Pressure: 9.78E-14mmHg at 25°C
• Melting Point: 182°C
• Boiling Point: 567.9°Cat760mmHg
• PKA: 12.79±0.70(Predicted)
• Flash Point: 297.3°C
• PSA: 99.38000
• Density: 1.454g/cm³
• LogP: 0.01850
• Storage Temp.: 2-8°C
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 306.11033829
• Heavy Atom Count: 22
• Complexity: 365

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Naphthylb-D-glucopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2OC3C(C(C(C(O3)CO)O)O)O
• Isomeric SMILES: C1=CC=C2C(=C1)C=CC=C2O[C@@H]3C([C@@H](C([C@@H](O3)CO)O)O)O

Technology Process of 1-Naphthylglucoside

There total 5 articles about 1-Naphthylglucoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

α-naphthol (90-15-3) → [1]naphthyl-galactopyranoside (19939-82-3,41335-32-4,65174-63-2,83833-13-0,84297-22-3,89157-92-6)

Guidance literature:

With potassium hydroxide; ethanol; <α-naphthyl>-d-galactoside;

Reference yield:

UDP-glucose (133-89-1) + 1,5-dihydroxynaphthalene (83-56-7) → 1-naphthol-β-D-glucopyranoside (19939-82-3)

Guidance literature:

With Aloe*arborescens*glycosyltransferase*GT₃; In dimethyl sulfoxide; at 30 ℃; for 12h; pH=7.4; Enzymatic reaction;

DOI:10.1016/j.tetlet.2017.04.041

Reference yield:

1-Naphthyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside (14581-88-5) → 1-naphthol-β-D-glucopyranoside (19939-82-3)

Guidance literature:

With methanol; sodium methylate;

upstream raw materials:

1-Naphthyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

UDP-glucose

1,5-dihydroxynaphthalene

α-naphthol

Refernces

• 1、 Tran, Linh T.,Blay, Vincent,Luang, Sukanya,Eurtivong, Chatchakorn,Choknud, Sunaree,González-Diáz, Humbert,Ketudat Cairns, James R.. "Engineering faster transglycosidases and their acceptor specificity". supporting information. p. 2823 - 2836. Retrieved 2019/06/13.