Mercaptooxy

Base Information

• Chemical Name: Mercaptooxy
• CAS No.: 62470-71-7
• Molecular Formula: HOS
• Molecular Weight: 49.0733
• Mol file: 62470-71-7.mol

Synonyms:

Chemical Property of Mercaptooxy

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Mercaptooxy

There total 4 articles about Mercaptooxy which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercapto radical (7704-34-9) + ozone (10028-15-6) → thioperoxy radical (62470-71-7) + hydroxyl (3352-57-6) + hydroperoxyl radical (7782-44-7)

Guidance literature:

In gaseous matrix; carrier gas: He; detd. by LMR spectroscopy;

DOI:10.1021/j100388a009

Reference yield:

mercapto radical (7704-34-9) → thioperoxy radical (62470-71-7) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

With Nitrogen dioxide; In gas; 298 K, low pressure (1-8 torr of He) discharge flow reactor; Kinetics;

DOI:10.1021/j100271a038

Reference yield:

mercapto radical (7704-34-9) + Nitrogen dioxide (10102-44-0) → thioperoxy radical (62470-71-7) + nitrogen(II) oxide (10102-43-9)

Guidance literature:

In gas; at 298 K in presence of a buffer gas; Kinetics;

DOI:10.1063/1.446838

upstream raw materials:

hydrogen sulfide

mercapto radical

Nitrogen dioxide

ozone

Downstream raw materials:

mercapto radical

Refernces

• 1、 Friedl, Randall R.,Brune, William H.,Anderson, James G.. "Kinetics of SH with NO2, O3, O2, and H2O2". . p. 5505 - 5510. Retrieved 2007/10/02.
• 2、 Singleton, Donald L.,Paraskevopoulos, George,Irwin, Robert S.. "Mechanism of the O(3P) + H2S Reaction. Abstraction or Addition?". . p. 2605 - 2609. Retrieved 2007/10/02.