2-broMo-4'-broMoMethylacetophenone

Base Information

• Chemical Name: 2-broMo-4'-broMoMethylacetophenone
• CAS No.: 62546-51-4
• Molecular Formula: C9H8Br2O
• Molecular Weight: 291.97
• Mol file: 62546-51-4.mol

Synonyms:2-Bromo-1-[4-(bromomethyl)phenyl]ethanone;

Chemical Property of 2-broMo-4'-broMoMethylacetophenone

Chemical Property:

• Boiling Point: 339 oC
• Flash Point: 118 oC
• PSA: 17.07000
• Density: 1.784
• LogP: 3.15910

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-bromo-1-[4-(bromomethyl)phenyl]ethanone 95%+ ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-broMo-4'-broMoMethylacetophenone

There total 2 articles about 2-broMo-4'-broMoMethylacetophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

para-methylacetophenone (122-00-9) → 1'-bromo-4-(bromomethyl)acetophenone (62546-51-4)

Guidance literature:

With N-Bromosuccinimide; tetrachlorosilane; In acetonitrile; at 20 ℃; for 6h;

DOI:10.1016/j.tetlet.2011.05.135

Reference yield:

→ 1'-bromo-4-(bromomethyl)acetophenone (62546-51-4)

Guidance literature:

4-Brommethyl-Verb., Br2 /Dioxan;

Reference yield: 60.0%

4,4'-bipyridine (553-26-4) + 1'-bromo-4-(bromomethyl)acetophenone (62546-51-4) → C29H24N4O(2+)*2PF6(1-)

Guidance literature:

4,4'-bipyridine; 1'-bromo-4-(bromomethyl)acetophenone; In acetonitrile; for 1h; Heating;

With ammonium hexafluorophosphate; In water; Further stages.;

DOI:10.1016/j.tet.2007.11.006

upstream raw materials:

para-methylacetophenone

Refernces