9-(4-broMophenyl)-10-phenylanthracene

Base Information

• Chemical Name: 9-(4-broMophenyl)-10-phenylanthracene
• CAS No.: 625854-02-6
• Molecular Formula: C26H17Br
• Molecular Weight: 409.325
• Hs Code.: 2903999090
• Mol file: 625854-02-6.mol

Synonyms:9-(4-bromophenyl)-10-phenyl-anthracene;Anthracene,9-(4-bromophenyl)-10-phenyl;9-phenyl-10-(4-bromophenyl)anthracene;

Chemical Property of 9-(4-broMophenyl)-10-phenylanthracene

Chemical Property:

• Melting Point: 225.0 to 229.0 °C
• Boiling Point: 505.4±19.0 °C(Predicted)
• PSA: 0.00000
• Density: 1.344±0.06 g/cm3 (20 oC 760 Torr)
• LogP: 8.08950
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: slightly sol. in Toluene

Purity/Quality:

99% ^*data from raw suppliers

9-(4-Bromophenyl)-10-phenylanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 9-(4-Bromophenyl)-10-phenylanthracene (cas# 625854-02-6) is a useful research chemical.

Technology Process of 9-(4-broMophenyl)-10-phenylanthracene

There total 10 articles about 9-(4-broMophenyl)-10-phenylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.1%

10-phenylanthracene-9-boronic acid (334658-75-2) + 1,4-bromoiodobenzene (589-87-7) → 9-(4-bromophenyl)-10-phenylanthracene (625854-02-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In 1,4-dioxane; water; toluene; for 12h; Reflux;

Reference yield: 72.0%

4-Bromophenylboronic acid (5467-74-3) + 9-iodo-10-phenylanthracene (150712-74-6) → 9-(4-bromophenyl)-10-phenylanthracene (625854-02-6)

Guidance literature:

With sodium carbonate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In water; toluene; at 110 ℃; for 10h;

Reference yield: 62.0%

4,4,5,5-tetramethyl-2-(10-phenylanthracen-9-yl)-1,3,2-dioxaborolane (460347-59-5) + 1,4-bromoiodobenzene (589-87-7) → 9-(4-bromophenyl)-10-phenylanthracene (625854-02-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1021/ja8042905

upstream raw materials:

4-Bromophenylboronic acid

9-iodo-10-phenylanthracene

4,4,5,5-tetramethyl-2-(10-phenylanthracen-9-yl)-1,3,2-dioxaborolane

1,4-bromoiodobenzene

Downstream raw materials:

4-(10-phenyl-9-anthryl)-4′-(9-phenyl-9H-carbazol-3-yl)triphenylamine

4-[4-(1-naphthyl)phenyl]-4'-(10-phenyl-9-anthryl)-4-(9-phenyl-9H-carbazol-3-yl)triphenylamine

4-(10-phenyl-9-anthryl)diphenylamine

1-(4-bromonaphthalen-1-yl)-4-(9-phenylanthracen-10-yl)benzene

Refernces

• 1、 -. "Pyrene derivatives having substituted groups and organic light-emitting diode including the same". . . Retrieved 2020/04/21.
• 2、 Huang, Zhiyuan,Xu, Zihao,Huang, Tingting,Gray, Victor,Moth-Poulsen, Kasper,Lian, Tianquan,Tang, Ming Lee. "Evolution from Tunneling to Hopping Mediated Triplet Energy Transfer from Quantum Dots to Molecules". supporting information. p. 17581 - 17588. Retrieved 2020/11/12.