Di-tert-butylchlorophosphine

Base Information Edit

Chemical Name:Di-tert-butylchlorophosphine
CAS No.:13716-10-4
Molecular Formula:C8H18ClP
Molecular Weight:180.658
Hs Code.:HOSPHINE PRODUCT IDENTIFICATION
DSSTox Substance ID:DTXSID70160089
Nikkaji Number:J101.881G
Wikidata:Q72469999
Mol file:13716-10-4.mol

Synonyms:Di-tert-butylchlorophosphine;13716-10-4;Di-tert-butylchlorophosphane;di-t-Butylchlorophosphine;ditert-butyl(chloro)phosphane;Phosphinous chloride, bis(1,1-dimethylethyl)-;Phosphinous chloride, di-tert-butyl-;Chlorodi-tert-butylphosphine;di-tert-butyl(chloro)phosphane;Di-tert-Butylphosphinous chloride;Phosphinous chloride, P,P-bis(1,1-dimethylethyl)-;MFCD00008815;ClPtBu2;P(tBu)2Cl;(tert-C4H9)2PCl;(t-Bu)2PCl;P(t-Bu)2Cl;chlorodi-t-butylphosphine;chlorobis-t-butylphosphine;chloro-di-t-butylphosphine;(Me3C)2P-Cl;chloro-di-tert-butylphosphine;di(tert-butyl)chlorophosphine;di-tert-butyl chlorophosphine;di-tert-butyl-chlorophosphine;ditert-butyl(chloro)phosphine;SCHEMBL56815;Di-tert-butylchlorophosphanec?;1-Boc- 4,4\'-bipiperidine;di-t-butyl phosphinous chloride;ditert-butyl(chloranyl)phosphane;DTXSID70160089;Di-tert-butylchlorophosphine, 96%;AMY42245;GEO-01258;AKOS015910830;BB 0221063;D3632;FT-0623660;D90210;EN300-158925;A807201;J-520404

Suppliers and Price of Di-tert-butylchlorophosphine

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Di-tert-butylchlorophosphine
1g
$ 55.00

TCI Chemical
Di-tert-butylchlorophosphine >95.0%(GC)
5g
$ 73.00

TCI Chemical
Di-tert-butylchlorophosphine >95.0%(GC)
25g
$ 244.00

Strem Chemicals
Di-t-butylchlorophosphine, min. 98%
25g
$ 181.00

Strem Chemicals
Di-t-butylchlorophosphine, min. 98%
1g
$ 25.00

Strem Chemicals
Di-t-butylchlorophosphine, min. 98%
5g
$ 100.00

Sigma-Aldrich
Di-tert-butylchlorophosphine 96%
100g
$ 881.00

Sigma-Aldrich
Di-tert-butylchlorophosphine 96%
5g
$ 103.00

Sigma-Aldrich
Di-tert-butylchlorophosphine 96%
25g
$ 229.00

Matrix Scientific
Di-tert-Butylchlorophosphine 95+%
5g
$ 152.00

Total 102 raw suppliers

Chemical Property of Di-tert-butylchlorophosphine Edit

Chemical Property:

Appearance/Colour:Colorless to light yellow liquid
Vapor Pressure:0.71mmHg at 25°C
Melting Point:2-3 °C
Refractive Index:n20/D 1.482(lit.)
Boiling Point:191.6 °C at 760 mmHg
Flash Point:61.1 °C
PSA：13.59000
Density:0.951 g/mL at 25 °C(lit.)
LogP:4.21910
Sensitive.:Air & Moisture Sensitive
Solubility.:Miscible with terahydrofuran.
XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:180.0834653
Heavy Atom Count:10
Complexity:93.4

Purity/Quality:

98% ^*data from raw suppliers

Di-tert-butylchlorophosphine ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 34
Safety Statements: 26-36/37/39-45-25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC(C)(C)P(C(C)(C)C)Cl
Uses Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions. Di-tert-butylchlorophosphine is used as a catalyst in organic synthesis. Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.

Technology Process of Di-tert-butylchlorophosphine

There total 15 articles about Di-tert-butylchlorophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%