Benzene, 1-decenyl-, (Z)-

Base Information

• Chemical Name: Benzene, 1-decenyl-, (Z)-
• CAS No.: 62839-72-9
• Molecular Formula: C16H24
• Molecular Weight: 216.367
• Mol file: 62839-72-9.mol

Synonyms:

Chemical Property of Benzene, 1-decenyl-, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzene, 1-decenyl-, (Z)-

There total 27 articles about Benzene, 1-decenyl-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

9-octyl-9-bora-bicyclo[3.3.1]nonane (30089-00-0) + (Z)-β-bromostyrene (588-73-8,1340-14-3) → (Z)-1-(dec-1-enyl)benzene (62839-72-9)

Guidance literature:

With sodium hydroxide; dihydrogen peroxide; cis-dichloro-1,1'-bis(diphenylphosphino)ferrocene palladium(II); In tetrahydrofuran; To a soln. of 9-octyl-9-BBN is added (C6H5)(CH)2Br, THF and aq. NaOH at room temp., mixt. refluxed overnight (14-16 h), react. mixt. diluted with hexane or benzene, residue oxidized by H2O2 at room temp.; Extracted, washed with brine, dried (MgSO4).;

DOI:10.1021/ja00183a048

Reference yield: 69.0%

1-phenyl-1-decyne (16664-50-9) → (Z)-1-(dec-1-enyl)benzene (62839-72-9) + (Z)-2-ethyl-1-phenyl-1-decene + (Z)-3-phenyl-3-dodecene

Guidance literature:

With diethylzinc; bis(acetylacetonate)nickel(II); In tetrahydrofuran; at -35 ℃; for 20h;

Reference yield: 9.0%

diethylzinc (557-20-0) + 1-phenyl-1-decyne (16664-50-9) → (Z)-1-(dec-1-enyl)benzene (62839-72-9) + (Z)-2-ethyl-1-phenyl-1-decene + (Z)-3-phenyl-3-dodecene

Guidance literature:

bis(acetylacetonate)nickel(II); In tetrahydrofuran; at -35 ℃; for 20h;

upstream raw materials:

1-bromo-octane

(Z)-β-bromostyrene

9-octyl-9-bora-bicyclo[3.3.1]nonane

nonan-1-al

Downstream raw materials:

(E)-1-phenyl-1-decene

Refernces

• 1、 Cheung, Chi Wai,Zhurkin, Fedor E.,Hu, Xile. "Z -selective olefin synthesis via iron-catalyzed reductive coupling of alkyl halides with terminal arylalkynes". supporting information. p. 4932 - 4935. Retrieved 2015/05/05.
• 2、 Wang, Jun,Guo, Xiangyu,Li, Chao-Jun. "Iridium as a general catalyst for the decarbonylative addition of aldehydes to alkynes". supporting information; experimental part. p. 211 - 215. Retrieved 2011/02/17.