Iodonium, bis(4-methoxyphenyl)-, iodide

Base Information

• Chemical Name: Iodonium, bis(4-methoxyphenyl)-, iodide
• CAS No.: 6293-71-6
• Molecular Formula: C14H14IO2.I
• Molecular Weight: 468.073
• DSSTox Substance ID: DTXSID90978749
• Mol file: 6293-71-6.mol

Synonyms:6293-71-6;Iodonium, bis(4-methoxyphenyl)-, iodide;Iodonium,bis(4-methoxyphenyl)-,iodide;Bis(4-methoxyphenyl)iodanium Iodide;SCHEMBL10788331;DTXSID90978749;bis(4-methoxyphenyl)iodanium;iodide

Chemical Property of Iodonium, bis(4-methoxyphenyl)-, iodide

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 467.90832
• Heavy Atom Count: 18
• Complexity: 184

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1=CC=C(C=C1)[I+]C2=CC=C(C=C2)OC.[I-]

Technology Process of Iodonium, bis(4-methoxyphenyl)-, iodide

There total 2 articles about Iodonium, bis(4-methoxyphenyl)-, iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

methoxybenzene (100-66-3) → 4,4'-dimethoxydiphenyliodonium iodide (6293-71-6)

Guidance literature:

methoxybenzene; With potassium iodate; sulfuric acid; iodine; In acetic anhydride; acetic acid; at 0 ℃; for 25h;

With potassium iodide; In water; acetic anhydride; acetic acid;

Reference yield:

→ 4,4'-dimethoxydiphenyliodonium iodide (6293-71-6)

Guidance literature:

With water; silver(l) oxide; anschliessendes Behandeln mit KI;

Reference yield: 88.0%

L-isoleucine methyl ester (2577-46-0) + 4,4'-dimethoxydiphenyliodonium iodide (6293-71-6) → (2S,3S)-methyl 2-((4-methoxyphenyl)amino)-3-methylpentanoate (1374027-60-7)

Guidance literature:

With silver nitrate; copper(I) bromide; In acetonitrile; at 90 ℃; for 4h; Inert atmosphere;

upstream raw materials:

methoxybenzene

Downstream raw materials:

5,5-bis(p-methoxyphenyl)-2,2-dimethyl-1,3-dioxan-4,6-dione

5-Benzyl-5-(4-methoxy-phenyl)-2,2-dimethyl-[1,3]dioxane-4,6-dione

dimethyl-dithiocarbamic acid 4-methoxy-phenyl ester

S-(4-methoxyphenyl) ethanethioate

Refernces

• 1、 Mckerrow, Jason D.,Al-Rawi, Jasim M.,Brooks, Peter. "Synthesis of some n-aryl α-Amino acids using diaryliodonium salts". experimental part. p. 1227 - 1236. Retrieved 2012/09/22.