Technology Process of Cyclohexanone, 3,3,5-trimethyl-5-(trimethylstannyl)-
There total 2 articles about Cyclohexanone, 3,3,5-trimethyl-5-(trimethylstannyl)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
hexamethyldistannane;
With
methyllithium;
In
tetrahydrofuran;
at -20 ℃;
for 0.25h;
3,5,5-Trimethylcyclohex-2-en-1-one;
In
tetrahydrofuran;
at 0 ℃;
for 0.5h;
- Guidance literature:
-
In
tetrahydrofuran;
a cold (-20°C) soln. of ((CH3)3SnCuSC6H5)Li in dry THF was allowed to react with (CH3)3C6H5O the mixt. was stirred under dry Ar atm. at -20°C for 15 min and at room temp. for 1 h;; the slurry (in mixt. of methanol and diethyl ether) was filtered through a short column of Florisil, then the column was eluted with diethyl ether; removal of the solvent by distn. (air-bath temp. 80-93°C/0.06 Torr); exact. mass given;;
- Guidance literature:
-
With
titanium tetrachloride;
In
dichloromethane;
at 0 ℃;
for 0.333333h;
Inert atmosphere;
