Tri-n-octyltin Hydride

Base Information

• Chemical Name: Tri-n-octyltin Hydride
• CAS No.: 869-59-0
• Molecular Formula: C24H52Sn
• Molecular Weight: 459.38
• Hs Code.: 2931900090
• European Community (EC) Number: 413-320-4
• UNII: 66Y856A2HM
• Mol file: 869-59-0.mol

Synonyms:Stannane, trioctyl-;Tri-n-octyltin Hydride;869-59-0;UNII-66Y856A2HM;66Y856A2HM;EC 413-320-4;trioctyltin;TIN, HYDROTRIOCTYL-;C24H52Sn;TRIS(N-OCTYL)STANNANE;(6-METHYL-2-PHENYL-IMIDAZO[1,2-A]PYRIDIN-3-YL)-ACETICACID

Chemical Property of Tri-n-octyltin Hydride

Chemical Property:

• Boiling Point: 463.4 °C at 760 mmHg
• Flash Point: 234.1 °C
• PSA: 0.00000
• Density: 0,99g/cm³
• LogP: 9.29500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 21
• Exact Mass: 459.301279
• Heavy Atom Count: 25
• Complexity: 188

Purity/Quality:

99.9% ^*data from raw suppliers

TRI-N-OCTYLTIN HYDRIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38-53-48/25-38
• Safety Statements: 26-36/37/39-61-45-36/37-23

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCC[Sn](CCCCCCCC)CCCCCCCC

Technology Process of Tri-n-octyltin Hydride

There total 8 articles about Tri-n-octyltin Hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

tri-n-octyl(phenyl)stannane (143363-50-2) + borane (13283-31-3) → tri-n-octyltin hydride (869-59-0)

Guidance literature:

In tetrahydrofuran; byproducts: phenylboronic acid; to srirred soln. of Sn-compound in THF was added soln. of BH3 in THF under N2, mixt. was left at room temp. for 1 h, refluxed for 1 h, cooled, Et2O and water was added; dried with MgSO4, solvent was removed under vac., column chromy. on silica gel with hexane and hexane-Et2O, recrystd. from water;

DOI:10.1016/S0022-328X(00)00536-2

Reference yield: 60.0%

trioctyltin chloride (2587-76-0) → tri-n-octyltin hydride (869-59-0)

Guidance literature:

With sodium tetrahydroborate; In propan-1-ol; at 20 ℃;

Reference yield: 40.0%

lithium aluminium tetrahydride (16853-85-3) + trioctyltin chloride (2587-76-0) → tri-n-octyltin hydride (869-59-0)

Guidance literature:

In diethyl ether;

upstream raw materials:

bis(trioctylstannyl) oxide

lithium aluminium tetrahydride

trioctyltin bromide

trioctyltin chloride

Refernces

• 1、 Faraoni,Koll,Mandolesi,Zú?iga,Podestá. "Transmetallations between aryltrialkyltins and borane: Synthesis of arylboronic acids and organotin hydrides". . p. 236 - 238. Retrieved 2007/10/03.