2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid

Base Information

• Chemical Name: 2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid
• CAS No.: 92549-65-0
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.274
• NSC Number: 191859
• DSSTox Substance ID: DTXSID10307512
• Mol file: 92549-65-0.mol

Synonyms:92549-65-0;NSC191859;DTXSID10307512;NSC-191859;2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid

Chemical Property of 2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid

Chemical Property:

• Vapor Pressure: 4.57E-10mmHg at 25°C
• Boiling Point: 481.1°Cat760mmHg
• Flash Point: 258.9°C
• Density: 1.391g/cm³
• XLogP3: 1.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 258.08920892
• Heavy Atom Count: 19
• Complexity: 435

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C2C=CC1C(C2C(=O)O)(C3=CC=CC=C3)C(=O)O

Technology Process of 2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid

There total 2 articles about 2-Phenylbicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-phenylmaleic anhydride (36122-35-7) + cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → 2-phenyl-norborn-5-ene-2,3-dicarboxylic acid (92549-65-0)

Guidance literature:

With benzene; anschliessend Behandeln mit wss. KOH oder Na₂CO₃;

DOI:10.1021/ja01160a015

Reference yield:

→ endo-cis-2-Phenyl-norbornen-(5)-dicarbonsaeure-(2,3) (92549-65-0,147753-40-0,147782-58-9,147782-64-7)

Guidance literature:

exo-2-Phenyl-endo-norbornen-(5)-dicarbonsaeure-(2,3)-anhydrid, Verseifen;

DOI:10.1021/jo01351a631

upstream raw materials:

2-phenylmaleic anhydride

cyclopenta-1,3-diene