N-Cyclohexylidenemethanamine

Base Information

• Chemical Name: N-Cyclohexylidenemethanamine
• CAS No.: 6407-35-8
• Molecular Formula: C7H13N
• Molecular Weight: 111.187
• Hs Code.: 2921300090
• Mol file: 6407-35-8.mol

Synonyms:cyclohexanone methylimine;N-methylcyclohexanone imine;cyclohexylidenemethylamine;N-cyclohexylidenemethylamine;Cyclohexyliden-methyl-amin;Methylamine,N-cyclohexylidene;Methanamine,N-cyclohexylidene;

Chemical Property of N-Cyclohexylidenemethanamine

Chemical Property:

• Boiling Point: 149.9±9.0 °C(Predicted)
• PKA: 7.71±0.20(Predicted)
• PSA: 12.36000
• Density: 0.92±0.1 g/cm3(Predicted)
• LogP: 2.02130

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N-Cyclohexylidenemethanamine

There total 4 articles about N-Cyclohexylidenemethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-cyclohexylidenemethanamine N-oxide (58751-78-3) + carbonic acid dimethyl ester (616-38-6) → cyclohexanone-oxime (100-64-1) + cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + N-cyclohexylidenemethylamine (6407-35-8)

Guidance literature:

With potassium carbonate; at 180 - 190 ℃; for 3h; Product distribution;

DOI:10.1021/jo00073a041

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + methylamine (74-89-5) → N-cyclohexylidenemethylamine (6407-35-8)

Guidance literature:

With potassium hydroxide;

Reference yield:

cyclohexanone (108-94-1,11119-77-0,9003-41-2,9075-99-4) + methylamine (74-89-5) → water (7732-18-5) + N-cyclohexylidenemethylamine (6407-35-8)

Guidance literature:

Equilibrium constant; in wss. Loesung vom pH 9.7 - 11.7;

upstream raw materials:

cyclohexanone

methylamine

N-cyclohexylidenemethanamine N-oxide

carbonic acid dimethyl ester

Downstream raw materials:

N-1-cyclohexenyl-N-methylcarbamyl chloride

1-(1-Cyclohexen-1-yl)-1-methyl-3-ethyl-2-thioharnstoff

N-Cyclohex-1-enyl-2-isopropyl-3,3,N-trimethyl-thiobutyramide

2,2,6,6-Tetramethyl-cyclohexanecarbothioic acid methylamide

Refernces

• 1、 Mas-Roselló, Josep,Hachisu, Shuji,Clayden, Jonathan. "Geometry-Retentive C-Alkenylation of Lithiated α-Aminonitriles: Quaternary α-Alkenyl Amino Acids and Hydantoins". supporting information. p. 10750 - 10754. Retrieved 2017/08/30.
• 2、 Tamura, Osamu,Matsukida, Hana,Toyao, Atsushi,Takeda, Yoshifumi,Ishibashi, Hiroyuki. "Is an iodine atom almighty as a leaving group for Bu3SnH-mediated radical cyclization? The effect of a halogen atom on the 5-endo-trig radical cyclization of N-vinyl-α-halo amides". . p. 5537 - 5545. Retrieved 2007/10/03.